GBZ42964-2023 English PDF

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GBZ42964-2023: Effectiveness of deacidification processes for paper-based literature in libraries
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Basic data

Standard ID: GB/Z 42964-2023 (GB/Z42964-2023)
Description (Translated English): Effectiveness of deacidification processes for paper-based literature in libraries
Sector / Industry: National Standard
Classification of Chinese Standard: A14
Classification of International Standard: 01.140.20
Word Count Estimation: 18,157
Date of Issue: 2023-08-06
Date of Implementation: 2023-08-06
Issuing agency(ies): State Administration for Market Regulation, China National Standardization Administration

GBZ42964-2023: Effectiveness of deacidification processes for paper-based literature in libraries

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GB /Z 42964-2023.Evaluation method for effectiveness of deacidification process of paper documents in libraries ICS 01.140.20 CCSA14 National Standardization Guiding Technical Documents of the People's Republic of China Method for evaluating the effectiveness of library paper document deacidification process Published on 2023-08-06 2023-08-06 Implementation State Administration for Market Regulation Released by the National Standardization Administration Committee

Table of contents

PrefaceⅠ Introduction II 1 Scope 1 2 Normative reference documents 1 3 Terms and Definitions 1 4 Principle 2 5 Requirements 3 5.1 Overview 3 5.2 Sampling 3 5.3 Process verification 3 5.4 Routine monitoring 6 6 Report 7 Appendix A (Informative) Side Effects and Disadvantages of Deacidification 8 Appendix B (informative) Paper sample inspection record form 9 B.1 Process verification test record form 9 B.2 Routine monitoring and testing records13 Reference 15

Foreword

This document complies with the provisions of GB/T 1.1-2020 "Standardization Work Guidelines Part 1.Structure and Drafting Rules of Standardization Documents" Drafting. This document is modified using ISO /T S18344.2016 "Effectiveness Evaluation of Deacidification Treatment of Paper Documents". The document type is determined by ISO 's technical specifications. The standard was adjusted as my country's national standardization guiding technical document. The technical differences between this document and ISO /T S18344.2016 and their reasons are as follows. ---The scope has been changed to conform to my country's national conditions; ---The term definition and English equivalent of alkali reserves have been changed (see 3.2), and the result units of alkali reserves have been changed (see Table 1, 5.3.3.3, 5.3.3.4, 5.3.3.5, 5.4.2.1), changed the terminology of degree of aggregation (see 3.3) to conform to my country’s national conditions; ---The standard basis for test paper filler types, test paper quantification, and acidity has been changed (see Table 1) to conform to my country's national conditions; ---Replaced ISO 9184-1 and ISO 9184-4 (see Table 1) with the normatively quoted GB/T 4688 to adapt to my country's technology condition; ---Replaced ISO 776 (see Table 1) with the normatively quoted GB/T 7978 to adapt to my country's technical conditions; ---Replaced ISO 536 (see Table 1) with the normatively cited GB/T 451.2 to adapt to my country's technical conditions; ---Replaced ISO 535 (see Table 1) with the normatively cited GB/T 1540 to adapt to my country's technical conditions; ---Replaced ISO 6588 (see Table 1) with the normatively quoted GB/T 1545 to adapt to my country's technical conditions; ---Replaced ISO 5630-5.2008 with normatively cited GB/T 40167-2021.The degree of consistency between the two documents is Modify (see 5.3.3.1) to adapt to my country’s technical conditions; ---Replaced ISO 10716 (see 5.3.3.3, 5.3.3.4 and 5.4.2.1) with normatively cited GB/T 24998 to adapt to my country's Technical conditions; ---Replaced ISO 5351.2010 with normatively cited GB/T 1548-2016, and the degree of consistency between the two documents is revised Modifications (see 5.3.3.5) to adapt to my country’s technical conditions; ---Replaced ISO 5626 (see 5.3.3.6) with the normatively cited GB/T 457 to adapt to my country's technical conditions; ---The number of papers used for deacidification uniformity testing has been changed (see Table 2) to meet the testing quality requirements. The following editorial changes have been made to this document. ---In order to coordinate with the existing standards, the name of the standard was changed to "Evaluation Method for Effectiveness of Deacidification Process of Library Paper Documents"; ---Deleted the "Note" in Table 1 (see Table 1); ---Change the intrinsic viscosity value in Table B.8 to the degree of polymerization (see Table B.8); ---Change the MIT folding endurance standard tensile force to 9.81N (see the note in 5.3.3.6). Please note that some content in this document may be subject to patents. The publisher of this document assumes no responsibility for identifying patents. This document is proposed by the Ministry of Culture and Tourism of the People's Republic of China. This document is under the jurisdiction of the National Library Standardization Technical Committee (SAC/TC389). This document was drafted by. National Library, Beijing Institute of Technology, Beijing Guotu Innovation Cultural Service Co., Ltd. The main drafters of this document. Tian Zhouling, Zhang Ming, Chen Hongyan, Zhao Yun, Feng Caihong, Zhang Lichao, and Li Nan.

Introduction

In accordance with the requirements of relevant laws, a large number of paper documents (manuscripts, printed copies, etc.) collected by libraries and other institutions need to be permanently preserved for the benefit of future generations. Class civilization. Acidification and hydrolysis of paper caused by acidic substances has become a difficult problem faced by libraries and other paper document collection units. paper acid One of the factors that change is that the early industrial papermaking process used acidic substances such as aluminum sulfate as additives for in-slurry sizing. These acidic substances encounter The water eventually forms free acid. Acid acts as a catalyst for fiber hydrolysis, causing the paper to become brittle. In addition, air pollution and cellulose degradation are also factors that paper The source of neutral acidic substances also aggravates the acidification of paper. Another factor in paper acidification is the stability of the raw material itself. Before industrial papermaking, flax, hemp or cotton were used to make paper. Textile fibers as raw materials. The cellulose molecular chains in these fibers are longer and relatively stable. In the process of looking for more types of raw materials, The process of making paper from groundwood pulp was invented. In addition to cellulose, groundwood pulp also retains most of the hemicellulose and lignin. Pulp purity Decrease and fiber cutting caused by mechanical processing lead to poor paper quality. Long-term stability of groundwood pulp paper compared to textile fiber pulp paper It is also poorer and more susceptible to acidification. Deacidification is to slow down the acidic degradation rate of paper by adding alkaline substances to neutralize acidic substances in the paper. Although it cannot Improve the original physical properties of paper, but under appropriate storage conditions, it can reduce the speed of aging in the future. People have been using single-page strips in the early days Acid process. Over the past few decades, new deacidification processes have emerged, and it is now possible to deacidify single pages or entire books in batches. This document presents suitable methods for evaluating the effectiveness of deacidification processes. This document does not specify which types of paper can be treated by batch deacidification. In order to avoid physical damage or other unnecessary side effects to paper and binding, no matter what deacidification method is currently used, there are always some The literature does not apply to deacidification processes. Deacidification techniques should be used to inform the library of the limitations of the chosen method. The potential side effects of the deacidification process on the literature are beyond the scope of this document. Only routine measures to deal with these side effects are given in Appendix A. suggestion. Unvalidated analytical methods cannot evaluate whether paper has been deacidified and how effectively it has been deacidified. Method for evaluating the effectiveness of library paper document deacidification process

1 Scope

This document describes test methods for evaluating the effectiveness and uniformity of deacidification processes for library paper documents and specifies minimum requirements. This document is suitable for batch deacidification process evaluation of printed or handwritten paper documents.

2 Normative reference documents

The contents of the following documents constitute essential provisions of this document through normative references in the text. Among them, the dated quotations For undated referenced documents, only the version corresponding to that date applies to this document; for undated referenced documents, the latest version (including all amendments) applies to this document. GB/T 451.2 Determination of basis weight of paper and paperboard (GB/T 451.2-2002, eqvISO 536.1995) GB/T 457 Determination of folding resistance of paper and paperboard (GB/T 457-2008, ISO 5626.1993, MOD) GB/T 1540 Determination of water absorption of paper and paperboard (Colbert method) (GB/T 1540-2002, neqISO 535.1991) GB/T 1545 Determination of acidity or alkalinity of aqueous extracts of paper, cardboard and pulp (GB/T 1545-2008, ISO 6588.1981, MOD) GB/T 1548-2016 Determination of intrinsic viscosity value in copper ethylenediamine (CED) solution in pulp (ISO 5351.2010, MOD) GB/T 4688 Analysis of fiber composition of paper, cardboard and pulp (GB/T 4688-2020, ISO 9184-1~9184-5.1990, MOD) GB/T 7978 Determination of acid-insoluble ash content of pulp (GB/T 7978-2005, ISO 776.1992, MOD) GB/T 24998 Determination of alkali reserves of paper and paperboard (GB/T 24998-2010, ISO 10716.1994, MOD) GB/T 40167-2021 Accelerated aging of paper and cardboard (100℃) (ISO 5630-5.2008, MOD)

3 Terms and definitions

The following terms and definitions apply to this document. 3.1 accelerated agingacceleratedaging Accelerate chemical reactions such as hydrolysis or oxidation in paper under laboratory conditions by increasing temperature, changing humidity, or exposing it to light. Application to simulate processes that usually occur slowly under natural conditions. 3.2 Alkalireserve alkalireserve The amount of alkaline compounds in paper and cardboard that can neutralize acids generated due to natural aging or atmospheric pollution. Note. For example, calcium carbonate and magnesium carbonate, use the method of GB/T 24998 to determine the alkali reserve, the unit is mole per kilogram (mol/kg). 3.3 The average number of anhydroglucose units (cellulose monomers) in cellulose macromolecules. 3.4 batchprocessbatchprocess A deacidification process that processes a certain or an indefinite number of documents at a time. ......

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