GB/T 41416-2022 PDF EnglishUS$170.00 · In stock · Download in 9 seconds
GB/T 41416-2022: Textiles - Determination of alpha-Bromo cinnamaldehyde and 1, 3-propanesultone Delivery: 9 seconds. True-PDF full-copy in English & invoice will be downloaded + auto-delivered via email. See step-by-step procedure Status: Valid
Similar standardsGB/T 41416-2022: Textiles - Determination of alpha-Bromo cinnamaldehyde and 1, 3-propanesultone---This is an excerpt. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.), auto-downloaded/delivered in 9 seconds, can be purchased online: https://www.ChineseStandard.net/PDF.aspx/GBT41416-2022NATIONAL STANDARD OF THE PEOPLE’S REPUBLIC OF CHINA ICS 59.080.01 CCS W 04 Textile -- Determination of alpha-bromocinnamaldehyde and 1,3-propanesultone ISSUED ON: APRIL 15, 2022 IMPLEMENTED ON: NOVEMBER 1, 2022 Issued by: State Administration for Market Regulation; Standardization Administration of PRC. Table of ContentsForeword ... 3 1 Scope ... 4 2 Normative references ... 4 3 Terms and Definitions ... 4 4 Principles ... 4 5 Reagents and materials ... 4 6 Instruments and equipment ... 5 7 Analysis steps ... 5 8 Result calculation ... 7 9 Limit of quantitation and precision ... 7 10 Test report... 8 Appendix A (Informative) GC-MS analysis conditions for 1,3-propanesultone and alpha-bromocinnamaldehyde ... 9 Appendix B (Informative) Total ion chromatogram of GC-MS analysis of 1,3- propanesultone and alpha-bromocinnamaldehyde ... 10 Textile -- Determination of alpha-bromocinnamaldehyde and 1,3-propanesultone Warning -- The personnel using this document shall have practical experience in formal laboratory work. This document does not indicate all possible safety issues. The user is responsible for taking appropriate safety and health measures and ensuring compliance with the conditions stipulated by relevant national laws and regulations.1 ScopeThis document describes a method for the determination of the content of alpha- bromocinnamaldehyde and 1,3-propanesultone in textiles by using the gas chromatography-mass spectrometry (GC-MS). This document applies to all types of textile products.2 Normative referencesThere are no normative references in this document.3 Terms and DefinitionsThere are no terms and definitions that need to be defined in this document.4 PrinciplesAfter ultrasonic extraction and filtration of the samples with ethyl acetate, determine it by the gas chromatography-mass spectrometer, qualitatively analyze it by the selected ion mode, and then quantitatively analyze it by the external standard method.5 Reagents and materialsUnless otherwise specified, the reagents used shall be of analytical grade. 5.1 Ethyl acetate. 5.2 Alpha-bromocinnamaldehyde (CAS No.: 5443-49-2): purity ≥99%. 5.3 1,3-propanesultone (CAS No.: 1120-71-4): purity ≥95%. 5.4 Standard stock solution: Accurately weigh an appropriate amount of alpha- bromocinnamaldehyde (5.2) and 1,3-propanesultone (5.3) reference materials respectively, and dilute them with ethyl acetate (5.1) respectively to prepare the standard stock solutions with a concentration of about 500 mg/L. Note: The standard stock solution shall be stored in the dark at 0 °C~4 °C, and the validity period is 6 months. 5.5 Mixed standard working solution: Accurately pipette a certain volume of standard stock solution (5.4) as needed, and dilute it stepwise with ethyl acetate (5.1) into a series of mixed standard working solutions with appropriate concentrations. Note: The mixed standard working solution shall be stored in the dark at 0 °C~4 °C, and it is valid for 1 month.6 Instruments and equipment6.1 Gas chromatography-mass spectrometer: It shall be equipped with an electron impact ion source (EI). 6.2 Balance: The division value shall be 0.1 mg and 0.01 g. 6.3 Temperature-controlled ultrasonic instrument: The temperature control range shall be 20 °C~60 °C, and the working frequency shall be (40±5) kHz. 6.4 Glass extraction tube with stopper: 100 mL. 6.5 Concentration bottle: It shall be 100 mL with a ground-glass stopper. 6.6 Rotary evaporator. 6.7 Nitrogen blower. 6.8 Organic filter membrane: 0.45µm.7 Analysis steps7.1 Preparation and treatment of specimens Take a representative sample, cut it into pieces with a size of less than 5 mm × 5 mm, and mix well. Accurately weigh 1.0 g of the above sample, and the weight shall be accurate to 0.01 g; place it in a 100 mL stoppered glass extraction tube (6.4), add 20 mL of ethyl acetate (5.1), and perform ultrasonic extraction for 20 min at (40±5) °C.8 Result calculation8.1 Calculate the content of alpha-bromocinnamaldehyde or 1,3-propanesultone in the sample according to formula (1): Where: X --- The content of alpha-bromocinnamaldehyde or 1,3-propanesultone in the sample, in milligrams per kilogram (mg/kg); A --- The peak area of alpha-bromocinnamaldehyde or 1,3-propanesultone in the sample solution; c --- The mass concentration of alpha-bromocinnamaldehyde or 1,3-propanesultone in the standard working solution, in milligrams per liter (mg/L); As --- The peak area of alpha-bromocinnamaldehyde or 1,3-propanesultone in the standard working solution; V --- The volume of the sample solution that is accurate to the scale, in milliliters (mL); m --- The mass of the sample, in grams (g). 8.2 The measurement results of this method are expressed as the calculation results of alpha-bromocinnamaldehyde and 1,3-propanesultone respectively, and the calculation results are rounded to one decimal place.9 Limit of quantitation and precision9.1 Limit of quantitation In this method, the limit of quantification of alpha-bromocinnamaldehyde is 0.2 mg/kg, and the limit of quantification of 1,3-propanesultone is 0.5 mg/kg. 9.2 Precision In the same laboratory, the same operator uses the same equipment, according to the same test method, and tests the same test object independently within a short period. The absolute difference between the two test results obtained shall be not greater than 10% of the arithmetic mean of the two measured values; take the confidence coefficient ......Source: Above contents are excerpted from the full-copy PDF -- translated/reviewed by: www.ChineseStandard.net / Wayne Zheng et al. Tips & Frequently Asked Questions:Question 1: How long will the true-PDF of English version of GB/T 41416-2022 be delivered?Answer: The full copy PDF of English version of GB/T 41416-2022 can be downloaded in 9 seconds, and it will also be emailed to you in 9 seconds (double mechanisms to ensure the delivery reliably), with PDF-invoice.Question 2: Can I share the purchased PDF of GB/T 41416-2022_English with my colleagues?Answer: Yes. The purchased PDF of GB/T 41416-2022_English will be deemed to be sold to your employer/organization who actually paid for it, including your colleagues and your employer's intranet.Question 3: Does the price include tax/VAT?Answer: Yes. 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