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GB/T 34609.1-2017 English PDF

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GB/T 34609.1-2017: Method for chemical analysis of rhodium compounds -- Part 1: Determination of rhodium content -- Gravimetric method with hexaammine cobalt nitrate
Status: Valid
Standard IDUSDBUY PDFLead-DaysStandard Title (Description)Status
GB/T 34609.1-2017199 Add to Cart 3 days Method for chemical analysis of rhodium compounds -- Part 1: Determination of rhodium content -- Gravimetric method with hexaammine cobalt nitrate Valid

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Basic data

Standard ID: GB/T 34609.1-2017 (GB/T34609.1-2017)
Description (Translated English): Method for chemical analysis of rhodium compounds -- Part 1: Determination of rhodium content -- Gravimetric method with hexaammine cobalt nitrate
Sector / Industry: National Standard (Recommended)
Classification of Chinese Standard: H15
Classification of International Standard: 77.120.99
Word Count Estimation: 10,110
Date of Issue: 2017-10-14
Date of Implementation: 2018-05-01
Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China

GB/T 34609.1-2017: Method for chemical analysis of rhodium compounds -- Part 1: Determination of rhodium content -- Gravimetric method with hexaammine cobalt nitrate


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Method for chemical analysis of rhodium compounds - Part 1. Determination of rhodium content - Gravimetric method with hexaammine cobalt nitrate ICS 77.120.99 H15 National Standards of People's Republic of China Methods for chemical analysis of rhodium compounds Part 1. Determination of rhodium content Ammonium hexammine cobalt gravimetric method Method for chemical analysis of rhodium compounds- Part 1.Determinationofrhodiumcontent- 2017-10-14 Published 2018-05-01 implementation General Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China China National Standardization Administration released

Foreword

GB/T 34609 "rhodium chemical analysis method" is divided into two parts. --- Part 1. Determination of rhodium content of hexamine cobalt nitrate gravimetric method; --- Part 2. Determination of platinum, palladium, iridium, ruthenium, gold, silver, lead, nickel, copper, iron, aluminum, magnesium, manganese, zinc, calcium, silicon, sodium, tin, Combined plasma atomic emission spectrometry. This section GB/T 34609 Part 1. This section drafted in accordance with GB/T 1.1-2009 given rules. This part is proposed by China Nonferrous Metal Industry Association. This part of the National Non-ferrous Metal Standardization Technical Committee (SAC/TC243) centralized. This section is responsible for the drafting unit. Your research Platinum Co., Ltd., your research and testing technology (Yunnan) Co., Ltd., non-ferrous metal technology economy Institute. This section participates in the drafting unit. Guangdong Provincial Industrial Analysis and Testing Center, Zhejiang Metallurgical Research Institute Co., Ltd., Chenzhou City, product quality Supervision and Inspection Institute, Jinchuan Group Co., Ltd. The main drafters of this section. Tao Sai Xiang, Yang Meiying, Luo Yijiang, Xiang Lei, Wang Teng, Qian Yanlin, Jin Yaqiu, Xing Yinjuan, Yang Hui, Gan Jian Zhuang, Zhao Wenhu, Ma Yuan, Fang Wei, Zhu Wuxun, Chen Xiaolan, Wang Fang, Wei Xiaojuan, Wang Shu Shu, Xiao Liu Ping, Zhou Jiao Lian, Ma Yuping, Zhou Zhiyong. Methods for chemical analysis of rhodium compounds Part 1. Determination of rhodium content Ammonium hexammine cobalt gravimetric method

1 Scope

GB/T 34609 provisions of this part of the determination of rhodium rhodium compounds. This section applies to rhodium nitrate (Rh (NO3) 3), rhodium sulfate (Rh2 (SO4) 3), rhodium trichloride (RhCl3), rhodium iodide (RhI3), rhodium acetate Rhodium octylate ([Rh (CH3 (CH2) 6CO2) 2] 2), rhodium acetylacetonate (C15H21O6Rh) Determination of rhodium content in triphenylphosphine rhodium chloride ([(C6H5) 3P] 3RhCl). Measurement range .5% ~ 50%.

2 method principle

The sample was pretreated with nitric acid, hydrochloric acid and perchloric acid, then digested in polytetrafluoroethylene tank and hydrochloric acid-hydrogen peroxide was digested under high temperature and high pressure, Chlorine complex slightly acidic solution, with rhodium nitrate hexamine cobalt complex precipitation, gravimetric determination of rhodium.

3 reagent

Unless otherwise specified, only reagents that are identified as analytically pure and secondary water are used in the analysis. 3.1 sodium nitrite. 3.2 Nitric acid (p = 1.42 g/mL). 3.3 Hydrochloric acid (p = 1.19 g/mL). 3.4 Absolute ethanol (ρ = 0.79g/mL). 3.5 ether (p = 1.19 g/mL). 3.6 perchloric acid (70.0% ~ 72.0%). 3.7 Hydrogen peroxide (30%, volume fraction). 3.8 Ammonium hexamine cobalt saturation solution Weigh 17g crystalline hexamine cobalt, add 300mL of water, heated to dissolve, with fast qualitative filter paper After filtration, dilute to 1000 mL. 3.9 Ammonium hexamine cobalt lotion Take 15mL hexamine cobalt saturated solution, diluted with water to 500mL. Note Preparation of hexamine cobalt nitrate in Appendix A.

4 device

Balance. Sense of 0.01mg.

5 sample

Samples stored in a closed container, the time is now.
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