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GB/T 17530.2-2023 English PDF

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GB/T 17530.2-2023: Test method of acrylic acid and acrylates for industrial use - Part 2: Determination of organic impurities and purity of acrylates for industrial use - Gas chromatography
Status: Valid

GB/T 17530.2: Historical versions

Standard IDUSDBUY PDFLead-DaysStandard Title (Description)Status
GB/T 17530.2-2023329 Add to Cart 4 days Test method of acrylic acid and acrylates for industrial use - Part 2: Determination of organic impurities and purity of acrylates for industrial use - Gas chromatography Valid
GB/T 17530.2-1998399 Add to Cart 3 days Determination of purity of industrial use acrylate esters by gas chromatography Obsolete

Similar standards

GB/T 16451   GB/T 17530.5   GB/T 17530.3   GB/T 17529.2   GB/T 17529.1   

Basic data

Standard ID: GB/T 17530.2-2023 (GB/T17530.2-2023)
Description (Translated English): Test method of acrylic acid and acrylates for industrial use - Part 2: Determination of organic impurities and purity of acrylates for industrial use - Gas chromatography
Sector / Industry: National Standard (Recommended)
Classification of Chinese Standard: G17
Classification of International Standard: 71.080.70
Word Count Estimation: 16,136
Date of Issue: 2023-11-27
Date of Implementation: 2024-06-01
Older Standard (superseded by this standard): GB/T 17530.2-1998
Issuing agency(ies): State Administration for Market Regulation, China National Standardization Administration

GB/T 17530.2-2023: Test method of acrylic acid and acrylates for industrial use - Part 2: Determination of organic impurities and purity of acrylates for industrial use - Gas chromatography


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
ICS 71:080:70 CCSG17 National Standards of People's Republic of China Replace GB/T 17530:2-1998 Test methods for industrial acrylic acids and esters Part 2: Organic acrylates for industrial use Determination of Impurities and Purity Gas Chromatography Published on 2023-11-27 2024-06-01 Implementation State Administration for Market Regulation Released by the National Standardization Administration Committee

Foreword

This document complies with the provisions of GB/T 1:1-2020 "Standardization Work Guidelines Part 1: Structure and Drafting Rules of Standardization Documents" Drafting: This document is Part 2 of GB/T 17530: GB/T 17530 has published the following parts: ---GB/T 17530:2 Test methods for industrial acrylic acid and esters Part 2: Organic impurities and purity of industrial acrylic acid esters Determination gas chromatography; ---GB/T 17530:3 Determination of color of industrial acrylic acid and ester; ---GB/T 17530:4 Determination of acidity of industrial acrylates; ---GB/T 17530:5 Determination of polymerization inhibitors in industrial acrylic acids and esters: This document replaces GB/T 17530:2-1998 "Gas Chromatography Method for Determination of Purity of Industrial Acrylates" and is consistent with GB/T 17530:2- Compared with:1998, in addition to structural adjustments and editorial changes, the main technical changes are as follows: ---Reagents and materials have been changed, butyl butoxypropionate and dichloromethane have been deleted, and methanol, methyl acetate, methyl propionate, etc: have been added: Agents and materials (see Chapter 5, Chapter 4 of the:1998 edition); ---The chromatographic analysis conditions were changed, the chromatographic column was changed from a packed column to a capillary column, and the chromatographic bars such as stationary solution, column temperature, and carrier gas flow rate were changed: (See Chapter 7, Chapter 6 of the:1998 edition); ---Changed the analysis result calculation formula (see Chapter 9, 7:4 and Chapter 8 of the:1998 edition); ---Deleted acrylate relative correction factor data (see Appendix A of the:1998 edition): Please note that some content in this document may be subject to patents: The publisher of this document assumes no responsibility for identifying patents: This document is proposed by China Petroleum and Chemical Industry Federation: This document is under the jurisdiction of the National Chemical Standardization Technical Committee (SAC/TC63): This document was drafted by: Satellite Chemical Co:, Ltd:, Wanhua Chemical Group Co:, Ltd:, Sinopec (Beijing) Chemical Research Institute Co:, Ltd:, Shanghai Huayi New Materials Co:, Ltd:, Pinghu Petrochemical Co:, Ltd:, Jiangsu Sandie Chemical Co:, Ltd:, Shandong Kaitai Petrochemical Co:, Ltd: CO:, LTD: The main drafters of this document: Cui Yaosen, Wang Zhigang, Huang Yu, Li Jun, Qian Ligang, Ma Yan, Zhang Aidong, Rosa, Xu Qilin, Zheng Shuai, Sun Zhijun, Jiang Tianya: This document was first published in:1998 and this is the first revision:

Introduction

GB/T 17530 aims to establish unified test methods for inspection items of industrial acrylic acid and ester, and with the development of analytical technology Update and improve upon development and maturity, testing the universality of project requirements: This series of standards has been established in the following four parts: ---GB/T 17530:2 Test methods for industrial acrylic acid and esters Part 2: Organic impurities and purity of industrial acrylic acid esters Determination by gas chromatography: A gas chromatograph equipped with a flame ionization detector is used to separate acrylate and various impurity components in Effective separation on the chromatographic column, and the purity of acrylate and the content of each impurity were calculated based on the correction area normalization method: ---GB/T 17530:3 Determination of color of industrial acrylic acid and ester: The sample is placed in a colorimetric tube and compared with the colorimetric value of the platinum-cobalt standard solution: Visual comparison: ---GB/T 17530:4 Determination of acidity of industrial acrylates: The sample is dissolved in ethanol, phenolphthalein is used as the indicator liquid, and hydrogen The sodium oxide standard titration solution is used to titrate the acid in the sample, and acrylic acid is used to measure the free acid in the sample: ---GB/T 17530:5 Determination of polymerization inhibitors in industrial acrylic acids and esters: It is to put p-hydroxyanisole in the sample in acidic medium React with nitrous acid to generate nitrous acid derivatives: Use a spectrophotometer to measure the absorbance at a wavelength of 420nm and standard curve: Quantitative: Test methods for industrial acrylic acids and esters Part 2: Organic acrylates for industrial use Determination of Impurities and Purity Gas Chromatography Warning---This document does not identify all possible safety issues: It is the user's responsibility to take appropriate safety and health measures and ensure compliance: Comply with the conditions stipulated in relevant national laws and regulations:

1 Scope

This document describes industrial methyl acrylate, industrial ethyl acrylate, industrial n-butyl acrylate and industrial 2-ethyl acrylate: Method for determination of organic impurities and purity in hexyl hexyl ester: This document applies to the corresponding ester products produced by the esterification reaction of acrylic acid with methanol, ethanol, n-butanol, and 2-ethylhexanol respectively: analyze:

2 Normative reference documents

The contents of the following documents constitute essential provisions of this document through normative references in the text: Among them, the dated quotations For undated referenced documents, only the version corresponding to that date applies to this document; for undated referenced documents, the latest version (including all amendments) applies to this document: GB/T 9722 General rules for gas chromatography with chemical reagents GB/T 17529:2 Acrylic acid and esters for industrial use Part 2: Methyl acrylate for industrial use GB/T 17529:3 Acrylic acid and esters for industrial use Part 3: Ethyl acrylate for industrial use GB/T 17529:4 Acrylic acid and esters for industrial use Part 4: n-Butyl acrylate for industrial use GB/T 17529:5 Acrylic acids and esters for industrial use Part 5: 2-Ethylhexyl acrylate for industrial use

3 Terms and definitions

There are no terms or definitions to be defined in this document:

4 Method summary

The acrylate sample passes through the chromatographic column, and each impurity is separated and detected by a hydrogen flame ionization detector: The organic impurities are normalized using a calibrated area: For quantification by the unified method, the acrylate content is calculated as 100% minus the mass fraction of organic impurities, moisture and acidity:

5 Reagents and materials

5:1 General provisions The reagents used in this document are of analytical grade reagents unless other requirements are noted:
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