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GB 5085.6-2007 English PDF

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GB 5085.6-2007: Identification standards for hazardous wastes Identification for toxic substance content
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Basic data

Standard ID: GB 5085.6-2007 (GB5085.6-2007)
Description (Translated English): Identification standards for hazardous wastes Identification for toxic substance content
Sector / Industry: National Standard
Classification of Chinese Standard: Z70
Classification of International Standard: 13.030.50
Word Count Estimation: 81,817
Date of Issue: 2007-04-25
Date of Implementation: 2007-10-01
Quoted Standard: HJ/T 298
Regulation (derived from): GB Notice 2007 No. 4 (No. 104 overall)
Issuing agency(ies): General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary: This Chinese standard relates to toxic, carcinogenic, mutagenic and reproductive toxic substances hazardous waste identification standards. For any production, life and other activities of solid waste generated toxic substances identified.

GB 5085.6-2007: Identification standards for hazardous wastes Identification for toxic substance content


---This is a DRAFT version for illustration, not a final translation. Full copy of true-PDF in English version (including equations, symbols, images, flow-chart, tables, and figures etc.) will be manually/carefully translated upon your order.
Identification standards for hazardous wastes Identification for toxic substance content ICS National Standards of People's Republic of China Identification standard for hazardous wastes Identification content of toxic substances Identification standards for hazardous wastes- Identification for toxic substance content (release draft) Posted 2007-04-25 2007-10-01 implementation State Environmental Protection Administration The State Administration of Quality Supervision, Inspection and Quarantine released

Table of Contents

Preface .III 1 Scope .1 2 Normative references ..1 3 Terms and Definitions .1 Identification standard 4 ..2 5 experimental method .. 3 6 Standards .. 3 Appendix A List of highly toxic substances ..4 Appendix B Toxic Substances ..6 Appendix C carcinogenic Substances ..12 Appendix D mutagenicity Substances .15 Appendix E reproductive toxicity Substances .16 Appendix F List of 17 persistent organic pollutants Appendix G semi-volatile organic compounds in the solid waste prior to sample analysis process accelerated solvent extraction 18 Appendix H N- methyl carbamate solid waste HPLC .22 Appendix I Determination of solid waste amitrole derivative - solid phase extraction - liquid chromatography-mass spectrometry usage .28 Fast Determination of Appendix J of solid waste paraquat and diuron HPLC UV method .31 Appendix K of solid waste and its selective aniline derivatives by gas chromatography .34 Determination of Appendix L of glyphosate solid waste HPLC Post - Column Derivatization fluorescence ..38 Determination of solid waste Solid Appendix M phenyl urea compounds phase extraction - High Performance Liquid Chromatographic Method .40 Determination of Appendix N of solid waste chlorinated herbicides methylation or five fluorobenzyl derivative gas chromatography ..44 Appendix O solid waste total recoverable petroleum hydrocarbons by infrared spectroscopy 58 Appendix P solid waste carbonyl compound by HPLC ..61 High performance liquid solid waste PAHs Appendix Q chromatography .68 Appendix R acrylamide solid waste by gas chromatography .71 Appendix S solid waste polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans Determination of High Resolution Gas Chromatography/scores Resolution mass spectrometry 75

Foreword

To implement the "People's Republic of China Environmental Protection Law" and "People's Republic of China Solid Waste Pollution Prevention Law" Environmental pollution prevention caused by hazardous waste, strengthen the management of hazardous waste, protect the environment, protect human health, the development of This standard. This standard is part of the national hazardous waste identification standard. National hazardous waste identification standard solid waste Hazardous characteristics Technical indicators hazardous characteristics standard technical specifications of solid waste are hazardous waste, required by law Hazardous waste management. National Hazardous Waste Identification standard consists of the following seven criteria consists of. 1, hazardous waste identification standard General 2. Identification standard for hazardous wastes Identification corrosion 3, hazardous waste identification standard acute toxicity screening 4. Identification of hazardous waste leaching toxic identification standard 5. Identification standard for hazardous wastes Identification Flammability 6, hazardous waste identification standard differential reactivity 7, hazardous waste identification standard differential toxic substance content This standard is the new part. According to relevant laws and regulations, the standard shall be enforceable. This standard was proposed by the State Environmental Protection Administration of Science, Technology. This standard was drafted. Chinese Research Academy of Environmental Sciences, Institute of solid waste pollution control technology, environmental standards research The, This standard SEPA March 27, 2007 for approval. This standard since October 1, 2007 implementation. This standard is interpreted by the State Environmental Protection Administration. Identification standard for hazardous wastes Identification content of toxic substances

1 Scope

This standard specifies the criteria to identify hazardous wastes containing toxic, carcinogenic, mutagenic and reproductive toxic substances. Identification of the content of toxic substances This standard applies to any production, life and other activities generated solid waste.

2 Normative references

The following documents contain provisions which, through GB 5085 of this standard reference and become the standard terms. Undated Reference documents, the latest versions apply to this standard. HJ/T 298 Identification of Hazardous Waste Technical Specifications

3 Terms and Definitions

The following terms and definitions apply to this standard. 3.1 Acutely toxic substance toxic substance It has a very strong toxicity of hazardous chemicals, including synthetic chemicals and natural toxins, and mixtures thereof. 3.2 Toxic substance toxic substance After ingestion, inhalation or skin may cause death or serious material damage to health after exposure. 3.3 Carcinogenic carcinogenic substance Substance can cause cancer or increase the cancer incidence. 3.4 Mutagenic substance mutagenic substance It can cause mutations in human germ cells and can be inherited substance. 3.5 Reproductive toxic substances reproductive toxic substance Have a detrimental effect on adult male or female sexual function and fertility and offspring development substances. 3.6 POPs persistent organic pollutants Toxic, biodegradable and bio-accumulation and other characteristics, by air, water and migratory species migrate long distances and Shen Accumulated during the deposition to terrestrial ecosystems and aquatic ecosystems accumulated organic chemicals. Identification standard 4 One of the following conditions are solid waste is hazardous waste. Appendix A contains 4.1 total content of one or more toxic substance ≥0.1% of this standard; 4.2 This standard contains a total content of Appendix B of one or more toxic substances ≥3%; 4.3 This standard contains a total content of Appendix C of one or more carcinogenic substances ≥0.1%; 4.4 This standard contains a total content of Appendix D of one or more mutagenic substances ≥0.1%; 4.5 This standard contains a total content of Appendix E of one or more substances toxic for reproduction of ≥0.5%; 4.6 This standard contains Appendices A to E of two or more different toxic substances, if the following equation, in accordance with Hazardous Waste Management. 1)] [(≥ Σ Tera Tera Muta Muta Carc Carc Where. PT - content of toxic substances in solid waste; PT - content of toxic substances in solid waste; PCarc - content of the solid waste carcinogenic substances; Content PMuta-- solid waste mutagenic substances; PTera - reproductive toxicity content of the solid waste material; LT, LT, LCarc, LMuta, LTera-- are standard values for various toxic substances prescribed in 4.1 to 4.5. 4.7 F containing any one of the persistent organic pollutants (except polychlorinated dibenzo-p-dioxins appendix to this standard, polychlorinated Benzofuran outside) content of ≥50 mg/kg; 4.8 content containing polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans ≥15 μg TEQ/kg.

5 Experimental Method

5.1 sampling sites and sampling methods according to HJ/298 performed. 5.2 Samples of inorganic elements and their compounds (except hexavalent chromium, inorganic fluorides, cyanides outside) pre-treatment methods, see GB 5085.3 Appendix S; sample pretreatment method hexavalent chromium and its compounds with reference to GB 5085.3 Appendix T. 5.3 Sample pretreatment methods of organic reference GB 5085.3 Appendix U, Appendix V, W and the appendix of this standard Appendix G. 5.4 Determination of various toxic substances, in addition to implementation of the provisions of the standard analytical methods, the method specified in Appendix Zanan execution; After the national environmental protection standards to be applied to measuring specific release of toxic substances, according to the standard implementation of the provisions.

6 Standards

This standard by the people's governments above the county level environmental protection administrative department responsible for overseeing implementation. Appendix A List of highly toxic substances Chinese name English name alias No. Chemical name CAS Number Analysis 1 thiophenol thiophenol; benzenethiol Thiophenol; Benzenethiol 108-98-5 GB 5085.3 Appendix K Acetone cyanohydrin 2 hydroxy-2-methyl-propionitrile; 2- Hydroxy-isobutyronitrile Acetone cyanohydrin; 2-Hydroxy-2-methylpropionitrile; 2-Hydroxuisobutyronitrile 75-86-5 GB 5085.3 Appendix O 2- 3 acrolein acrolein; lose fat aldehyde Acrolein; 2-Propenal 107-02-8 GB 5085.3 Appendix O 4 acrylate, 2-acrylic acid Acrylic acid; 2-Propenoic acid 79-10-7 GB 5085.3 Appendix I 5 carbofuran Wei Kaba furan; 2,3-dihydro-2,2 Dimethyl-7-benzofuranyl -N- Methylcarbamate Furadan; Carbofuran; 2,2-Dimethyl-2,3-dihydro-7-benzofuran yl N-methylcarbamate 1563-66-2 GB 5085.3 attached Record K, Appendix H of this standard 6 high mercury iodide, mercury iodide; diiodide mercury Mercuric iodide; Mercury diiodide 7774-29-0 GB 5085.3 Appendix B 7 thallium iodide, thallium iodide; a thallium iodide Thallium iodide; Thallous iodide 7790-30-9 GB 5085.3 attached Record A, B, C, 8 dinitro-o-cresol methyl-4,6-dinitrophenol Dinitro-ortho-cresol; 2-Methyl-4,6-dinitrophenol 534-52-1 GB 5085.3 attached Record K 9 selenite selenium dioxide Selenium dioxide; Selenious acid 7783-00-8 GB 5085.3 Appendix B, C, E 10 phorate O, O - diethyl -S- (ethylthio Methyl) phosphorodithioate; three Nine hundred eleven Phorate; O, O-Diethyl S- (ethylthio) methyl phosphorodithioate 298-02-2 GB 5085.3 Appendix I, K, L 11 phosphamidon chloro-2-diethylcarbamoyl Methylethenyl dimethylphosphorane Esters; large pest control Phosphamidon; 2-Chloro-2-diethylcarbamoyl-1-methylv inyl dimethylphosphate 13171-21-6 GB 5085.3 Appendix I, K 12 mercuricthiocyanate two mercuricthiocyanate Mercuric thiocyanate; Mercury dithiocyanate 592-85-8 GB 5085.3 attached

Appendix B

13 mercuric chloride mercury chloride (II); mercuric chloride Mercuric chloride; Mercury (II) chloride; Mercury dichloride 7487-94-7 GB 5085.3 attached

Appendix B

14 selenium chloride monochloride selenium Selenium chloride; Selenium monochloride; 10025-68-0 GB 5085.3 attached Record B, C, E 15 thallium chloride, thallium chloride Thallous chloride; Thallium chloride 7791-12-0 GB 5085.3 attached Record A, B, C, Methomyl 16 1- (methylthio) ethylene ammonia Methylcarbamate; Off Buggy; off voioe Methomyl; 1- (Methylthio) ethylideneamino methylcarbamate 16752-77-5 GB 5085.3 attached Record L, Appendix H of this standard 17 two cyanide barium cyanide Ba Barium cyanide; Barium dicyanide 542-62-1 GB 5085.3 Appendix G 18 calcium cyanide - Calcium cyanide; Calcyanide 592-01-8 GB 5085.3 Appendix G 19 two mercury cyanide cyanide mercury Mercuric cyanide; Mercury dicyanide 592-04-1 GB 5085.3 Appendix G 20 potassium cyanide hydrocyanic acid potassium salt; kaempferol potassium Potassium cyanide; Hydrocyanic acid, Potassium salt 151-50-8 GB 5085.3 attached Record G 21 hydrocyanic acid sodium salt; kaempferol; Mountain Sodium Chennai Sodium cyanide; Hydrocyanic acid, sodium salt 143-33-9 GB 5085.3 attached Record G 22 two zinc cyanide zinc cyanide Zinc cyanide; Zinc dicyanide 557-21-1 GB 5085.3 Appendix G Chinese name English name alias No. Chemical name CAS Number Analysis 23 cyanide cuprous cyanide copper (I) Cuprous cyanide; Copper (I) cyanide 544-92-3 GB 5085.3 Appendix G 24 copper cyanide, sodium cyanide, sodium copper; copper salt Sodium cuprocyanide; Copper sodium cyanide 14264-31-4 GB 5085.3 attached Record G 25 silver cyanide silver cyanide (1) Silver cyanide; Silver (1) cyanide 506-64-9 GB 5085.3 Appendix G 26 triiodide Arsenic iodide Arsenic Arsenic triiodide; Arsenous iodide 7784-45-4 GB 5085.3 Appendix C, E 27 arsenic trichloride chloride arsenite Arsenic trichloride; Arsenous chloride 7784-34-1 GB 5085.3 Appendix C, E 28 arsenite (elemental arsenic Objective analysis to the compound Basis) Original sodium arsenate; arsenic acid trisodium salt Sodium arsenate; Arsenic acid, trisodium salt 7631-89-2 GB 5085.3 Appendix C, E 29 tetraethyl lead - Lead tetraethyl; Plumbane, tetraethyl- 78-00-2 GB 5085.3 attached Record A, B, C, 30 thallium metal thallium Thallium; Thallium metal 7440-28-0 GB 5085.3 attached Record A, B, C, 31 carbon chlorine spirit octachlorohepta hexahydro methylene isobenzofuran Furan; carbon chlorine Trane Isobenzan; Octachloro-hexahydro-methanoisobenzo furan 297-78-9 GB 5085.3 Appendix K 32 nickel carbonyl nickel tetracarbonyl Nickel carbonyl; Nickel tetracarbonyl 13463-39-3 GB 5085.3 attached Record A, B, C, 33 Aldicarb methyl-2- (methylthio Yl) -O - ((methylamino) methyl group) Oxime; aldicarb; tears Mieke Aldicarb; Propanal, 2-methyl-2- (methylthio) -, O - ((methylamino) carbonyl) oxime 116-06-C Appendix H of this standard 34 CdSe - Cadmium selenide 1C06-24-7 GB 5085.C attached Record A, B, C, 35 mercurous nitrate mercuric nitrate (monohydrate) Mercurous nitrate; Mercurous nitrate (monohydrate) 7782-86-7 GB 5085.3 attached

Appendix B

Thallium bromide 36 - Thallous bromide 7789-40-4 GB 5085.3 attached Record A, B, C, 37 tellurite sodium (as elemental tellurium In order to analyze the goal, that of Compound meter) Three oxygen telluric acid disodium Sodium tellurite; Disodium trioxotellurate 10102-20-2 GB 5085.3 Appendix B Arsenite 38 Asia (elemental arsenic In order to analyze the goal, that of Compound meter) Sodium arsenite; partial arsenite Sodium arsenite; Arsenenous acid, sodium salt; Sodium metaarsenite 7784-46-5 GB 5085.3 Appendix C, E 39 Nicotine Nicotine; 1-methyl-2- (3-pyrazol Piperidyl) pyrrolidine Pyridine; Nicotine; 1-Methyl-2- (3-pyridyl) pyrrolidine 54-11-5 GB 5085.3 attached Record K Appendix B List of Toxic Substances No. Chinese name Alias English name Chemical name CAS Number Analysis 1 aminotriazole amitrole Aminotriazole; Amitrole 61-82-5 Appendix I of this standard 2 palladium sponge (like) palladium Palladium; Palladium sponge 7440-05-3 GB 5085.3 Appendix B 3 paraquat 1,1-dimethyl-4,4 - bipyridine Dichloride; paraquat Paraquat; 4,4'-Bipyridinium, 1,1'-dimethyl-, dichloride 1910-42-5 this standard appendix A0 4 chlorothalonil 2,4,5,6-tetrachloro-1,3-isophthalonitrile Chlorothalonil; 1,3-Benzenedicarbonitrile, 2,4,5,6-tetrachloro- 1897-45-6 GB 5085.3 Appendix H, K 5 fenthion O, O- dimethyl methylthio -O-4- Intergenerational tolyl phosphorothioate Ester; one hundred rule Tu; Fan parathion Fenthion; O, O-Dimethyl O-4-methylthio-m-tolyl phosphorothioate 55-38-9 GB 5085.3 Appendix I, K 6 aniline amino benzene Aniline; Aminobenzene; Benzeneamine 62-53-3 Appendix K of this standard 7 1,4-phenylenediamine p-phenylene diamine; 1,4-diaminobenzene 1,4-Phenylenediamine; p- Phenylenediamine; 1,4-Diaminobenzene 106-50-3 GB 5085.3 Appendix K 8 1,3-hydroquinone, resorcinol; resorcinol 1,3-Benzenediol; m-Benzenediol; Resorcin 108-46-3 GB 5085.3 attached Record K 9 1,4-hydroquinone hydroquinone; hydroquinone 1,4-Benzenediol; p-Benzenediol; Hydroquinone; 123-31-9 GB 5085.3 attached Record K 10 phenylhydrazine hydrazine benzene Phenylhydrazine; Hydrazobenzene 100-63-0 GB 5085.3 Appendix K 11 Benomyl benzene to special Benomyl; Benlate 17804-35-2 GB 5085.3 Appendix L 12 benzoquinone benzoquinone; 1,4-cyclohexadiene-dione Quinone; p-Quinone; 1,4-Cyclohexadienedione 106-51-4 GB 5085.3 attached Record K 13 Styrene divinylbenzene Styrene; Vinyl benzene 100-42-5 GB 5085.3 Appendix O, P 14 epichlorohydrin 1-chloro-2,3-propylene oxide; ethylene Chloropropane Epichlorohydrin; 1-Chloro-2,3-epoxypropane 106-89-8 GB 5085.3 attached Record O, P 15 Acetone 2-propanone Acetone; 2-Propanone 67-64-1 GB 5085.3 Appendix O 16 platinum sponge (like) platinum; platinum Platinum; Platinum sponge 7440-06-4 GB 5085.3 Appendix B 17 Glyphosate N- (phosphorus) glycine; town Glyphosate Glyphosate; N- (Phosphonomethyl) glycine 1071-83-6 The Standard Appendix L 18 Diflubenzuron 1- (4-chlorophenyl) -3- (2,6-difluoro Benzoyl) urea; V urea kill, Insecticidal urea, di-fluorouracil Diflubenzuron; 1- (4-Chlorophenyl) -3- (2,6-difluorobenz oyl) urea 35367-38-5 The Standard Appendix M 19 2,4 (content > 75%) of 2,4-dichlorophenoxyacetic acid 2,4-D (content > 75%); 2,4-Dichlorophenoxyacetic acid 94-75-7 GB 5085.3 attached Record L, The Standard Appendix N Trichlorfon 20 Dimethyl (2,2,2-trichloro-1-hydroxyethyl Yl-ethyl) phosphonate Trichlorfon; Dimethyl (2,2,2-trichloro-1-hydroxyethy l) phosphonate 52-68-6 GB 5085.3 Appendix I, L 21 diquat diquat; 1,1'-ethylidene - 2,2'-dibromo pyridine salt Diquat; Diquat dibromide; 1,1'-Ethylene 2,2'-bipyridylium dibromide 85-00-7 Appendix J of this standard Diuron 22 N- (3,4- dichloro-phenyl) -N ', N'- Dimethylurea Diuron; N- (3,4-Dichlorophenyl) -N ', N'-dimethyl urea 330-54-1 GB 5085.3 attached Record L, This standard appendix 23 dichlorvos O, O - dimethyl - O - (2,2- Dichlorophenyl) vinyl phosphate Dichlorvos; O, O-Dimethyl-O- (2,2-dichloro) vinyl phosphate 62-73-7 GB 5085.3 Appendix I, K, L No. Chinese name Alias English name Chemical name CAS Number Analysis 241- butanol butanol 1-Butanol; n-Butanol 71-36-3 GB 5085.3 Appendix O 252- butanol, sec-butanol 2-Butanol; sec-Butanol 78-92-2 GB 5085.3 Appendix O Iso-propanol, butanol, 2-methyl Isobutanol; 2-Methyl propanol 78-83-1 GB 5085.3 Appendix O 1,1-dimethyl ethanol, tert-butanol tert-Butyl alcohol; 1,1-Dimethylethanol 75-65-0 GB 5085.3 Appendix O 27 propachlor -N- isopropyl-2-chloro-acetanilide Propachlor; 2-Chloro-N-isopropylacetanilide 1918-16-7 GB 5085.3 attached L record 28 Carbendazim Cotton Xiaoweiling Carbendazim; Carbendazol 4697-36-3 GB 5085.3 Appendix L Over 29, barium sulfide, barium sulfide; sulfur mixture of barium Barium polysulfide; Barium sulfide 50864-67-0 GB 5085.3 attached Record A, B, C, 30 1,1-diphenyl hydrazine N, N- diphenyl linked amine 1,1-Diphenylhydrazine; N, N-Diphenylhydrazine 530-50-7 GB 5085.3 attached Record K 31 N, N- dimethylaniline (dimethylamino) benzene, N, N-Dimethylaniline; (Dimethylamino) benzene 121-69-7 GB 5085.3 attached Record K 32 dimethylphenol xylenol Dimethyl phenol; Xylenol 1300-71-6 GB 5085.3 Appendix K 33 dimethylformamide N, N- Dimethylformamide dimethyl formamide; N, N-Dimethylformamide 68-12-2 GB 5085.3 attached Record K 34 o-dichlorobenzene, 1,2-dichlorobenzene 1,2-Dichlorobenzene; o-Dichlorobenzene 95-50-1 GB 5085.3 attached Record K, O, P, 35 1,3-dichlorobenzene-dichlorobenzene 1,3-Dichlorobenzene; m-Dichlorobenzene 541-73-1 GB 5085.3 attached Record K, O, P, 36 1,4-dichlorobenzene dichlorobenzene 1,4-Dichlorobenzene; p-Dichlorobenzene 106-46-7 GB 5085.3 attached Record K, O, P, 37 2,4-dichloro-aniline 2,4-DCA 2,4-Dichloroaniline; 2,4-Dichlorobenzenamine 554-00-7 of the Standard Appendix K 38 2,5-dichloro-aniline to dichloroaniline 2,5-Dichloroaniline; p-Dichloroaniline 95-82-9 Appendix K of thi......
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