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HJ 2546-2016 Related PDF English

HJ 2546-2016 (HJ2546-2016) & related versions
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HJ 2546-2016English349 Add to Cart 3 days Technical requirement for environmental labeling products Textile products HJ 2546-2016 Valid HJ 2546-2016



HJ 2546-2016 (Environmental labeling products Technical requirements Textile products) National Environmental Protection Standard of the People 's Republic of China Replacing HJ/T 307-2006, HJ/T 309-2006 Environmental labeling products Technical requirements Textile products Technical requirement for environmental labeling products Textile products 2016-11-14 release 2017-01-01 Implementation Ministry of Environmental Protection released Directory Preface ..II 1 Scope of application 1 2 normative reference document 1 3 terms and definitions 4 basic requirements 2 5 technical content 2 6 test method 4 Appendix A (normative) carcinogenic aromatic amines Appendix B (normative) Prohibited use of carcinogenic dyes 7 Appendix C (normative) prohibits the use of sensitized disperse dyes Appendix D (normative) Restricted use of chlorinated phenol 9 Annex E (normative) restrictions on the use of chlorobenzene and chlorinated toluene 9 Appendix F (normative) Restricted use of phthalate 10 Appendix G (normative) Restricted use of PAHs 11 Preface To implement the "People's Republic of China Environmental Protection Law" to reduce the textile products in the production and use of the environment and human health Influence, protect the environment, develop this standard. This standard on the production of textile products, products, toxic and hazardous substances and product packaging and other requirements. This standard will be "environmental labeling products technical requirements eco-textiles" (HJ/T 307-2006) and "environmental labeling products technology (HJ/T 309-2006), the main changes are as follows. - Adjusted the standard name and scope of application; - Increased requirements for baking of surfactants and asbestos fibers in raw materials - Increased restrictions on the use of coating finishing agents and hazardous substances in the coloring process used in the production process; - Added dyes, insecticides, flame retardant finishing agents, chlorinated benzene and chlorinated toluene, phthalates, organotin compounds Disable category - Adjusted formaldehyde requirements; - Increased total lead, total cadmium content, polycyclic aromatic hydrocarbons, perfluorinated compounds, residual surfactants, fumaric acid di Methyl ester requirements; - increased product packaging requirements; - Removes the requirements of antibacterial finishing agents, color fastness, volatile substances, metal sharp objects; - Adjust the inspection method. This standard is organized by the Ministry of Environmental Protection Science and Technology Standards Division. The main drafting unit of this standard. Environmental Development Department of Environmental Protection, Textile Industry Southern Science and Technology Testing Center, Jiangsu Entry and Exit Inspection Inspection and Quarantine Bureau of textile industry product testing center, reputation standard detection (Shenzhen) Co., Ltd., Guangdong Esquel Textile Co., Ltd., Zhejiang hi Po Silk Technology Co., Ltd., Zhejiang Furun Printing and Dyeing Co., Ltd., Huzhou Zhenbei Cashmere Products Co., The environmental protection department of this standard approved on November 14,.2016. This standard has been implemented since January 1,.2017. This standard is explained by the Ministry of Environmental Protection. This standard replaced the previous version of the standard release. - HJ/T 307-2006, HJ BZ 30-2000, HJ BZ 30-1998, HJ BZ 005-1994; - HJ/T 309-2006, HJ BZ 11-1996. Environmental labeling products Technical requirements Textile products 1 Scope of application This standard specifies the terms and definitions, basic requirements, technical contents and test methods for textile product environmental labeling products. This standard applies to all types of textile products. 2 normative reference documents The contents of this standard refer to the terms of the following documents. For undated references, the valid version applies to this standard. Technical specification for basic safety of national textile products GB 18401-2010 Technical code for safety of infant and children 's textile products GB 31701-2015 GB/T 2912.1-2009 Textiles - Determination of formaldehyde - Part 1. Free hydrolysis of formaldehyde (water extraction) Textiles - Determination of pH value of aqueous extract Textiles - Determination of heavy metals GB/T 17593-2006 GB/T 18414.1-2006 Textiles - Determination of chlorinated phenol - Part 1. Gas chromatography - mass spectrometry Textiles - Determination of chlorophenol - Part 2. Gas chromatographic method GB/T 18414.2-2006 GB/T 18455 Packaging Recycling Mark Technical requirements for eco - textiles GB/T 18885 Textiles - Determination of benzene and chlorinated toluene residues GB/T 20384-2006 Textiles - Determination of organotin compounds GB/T 20385-2006 Textiles - Determination of o - phenylphenol GB/T 20386-2006 Textiles - Determination of phthalate esters GB/T 20388-2006 Textiles - Determination of surface active agent - Alkylphenol ethoxylates GB/T 23322-2009 GB/T 23972-2011 Determination of alkylphenols and alkylphenol polyoxyethylene ethers in textile dyeing and finishing aids High performance liquid chromatography / Mass spectrometry Paints and varnishes - Determination of volatile organic compounds (VOC) content - Gas chromatographic method GB/T 23986-2009 GB/T 23986-2009 Textiles - Determination of polycyclic aromatic hydrocarbons (PAHs) GB/T 28189-2011 GB/T 28190-2011 Textiles - Determination of dimethyl fumarate Textiles - Determination of total lead and total cadmium content GB/T 30157-2013 HJ 2541 Environmental labeling products Technical requirements Adhesives HJ/T 185-2006 Cleaner Production Standard Textile (Cotton Printing and Dyeing) HJ/T 359-2007 Clean production standard Chemical fiber industry (polyester) HJ/T 429-2008 Clean production standard Chemical fiber industry (spandex) SN/T 2842-2011 Determination of perfluorooctane sulfonate and perfluorooctanoic acid in textiles by liquid chromatography tandem mass spectrometry 3 terms and definitions The following terms and definitions apply to this standard. 3.1 textile products To natural fiber and/or chemical fiber as the main raw material, by spinning, weaving, dyeing and other processing technology or by sewing, composite and other processes made Products such as yarns, fabrics and their finished products. (GB 18401-2010) 3.2 Infant Textile Products textile products for infants The age of 36 months and below the infants wear or use of textile products. (GB 18401-2010) 3.3 children's textile products textile products for children Textiles for children aged 3 years and older and children 14 years of age or older Note 1. (GB 31701-2015) Note 1. Generally apply to the height of 100cm or more, 155cm and below girls or 160cm and below the boys wearing or use the textile Products can be used as children's textile products. Among them, 130cm and below children can be seen as children under the age of 7 clothing. (GB 31701-2015) 3.4 Textile products with direct contact with skin In the wearing and use of the product, most of the area directly with the human skin contact with the textile products. (GB 18401-2010) 3.5 Textile products that are not directly exposed to skin textile products without direct contact to skin When dressed and used, the product is not directly in contact with human skin, or only a small area of direct contact with the human skin in contact with the textile product. (GB 18401-2010) 3.6 Decorative textile products Decorative textile products For decorative products (such as tablecloths, wall covering, curtains, carpets, etc.). 4 basic requirements 4.1 product quality, safety performance should meet the requirements of the corresponding standards. 4.2 The pollutant discharge of the product manufacturer shall conform to the pollutant discharge standard stipulated by the state or local. 4.3 production process should strengthen the clean production, which spandex, polyester and cotton printing and dyeing enterprises should be clean production level HJ/T 429-2008, HJ/T 359-2007, HJ/T 185-2006 Secondary standard requirements. 5 technical content 5.1 Requirements for the production process 5.1.1 The substances listed in Table 1 are not used in the production of textile products. Table 1 Prohibited substances used in the production of textile products Category Prohibited substances used in the production process dye Can be decomposed carcinogenic aromatic amine azo dyes (carcinogenic aromatic amine see Appendix A), carcinogenic dye (see attached Recorded B), sensitizing disperse dyes (see Appendix C) Flame retardant finishing agent Polybrominated biphenyls (PBB), tris- (2,3-dibromopropyl) -phosphate (TRIS), triethyl phosphonoacetate (TEPA), pentabromodiphenyl ether (PeBDE), octabromodiphenyl ether (OcBDE), decabromodiphenyl ether (HBCDD), short chain chlorinated paraffins (SCCP), tris (2- Carboxyethyl) phosphine (TCEP) Surfactant Alkylphenol polyoxyethylene ethers (APEOs), nitrilotriacetic acid (NTA), bis (hydrogenated tallow alkyl) Dimethyl ammonium chloride (DTDMAC), distearyl dimethyl ammonium chloride (DSDMAC), di Butter) dimethyl ammonium chloride (DHTDMAC), ethylenediamine tetraacetate (EDTA) and diethyl Triamine Pentaacetate (DTPA) Fiber asbestos 5.1.2 Hazardous substances in solvent-based coating agents shall meet the requirements of the corresponding categories in the HJ 2541 standard. 5.1.3 The volatile organic compounds (VOCs) in the printing paste should be no more than 5%. 5.2 Requirements for Hazardous Substances in Products 5.2.1 The total amount of pesticide in natural textile products should meet the requirements of GB/T 18885. 5.2.2 The limit of hazardous substances in textile products shall meet the requirements of Table 2. Table 2 Restrictions on Hazardous Substances in Textile Products classification Test items Infant textile production Children and direct contact Skin textile products Non-direct contact with skin Skin and decorative spinning Woven products PH 4.0-7.5 4.0-7.5 4.0-9.0 Formaldehyde, mg/kg ≤ Not detected 30.0 75.0 Extractable Heavy metals, Mg/kg ≤ Arsenic (As) 0.2 1.0 Lead (Pb) 0.2 1.0 Chromium (Cr) 1.0 2.0 Co (Co) 1.0 4.0 Copper (Cu) 25.0 50.0 Nickel (Ni) 1.0 4.0 Chromium (Cr) (Ⅵ) may not be detected Cadmium (Cd) 0.1 Antimony (Sb) 30.0 Mercury (Hg) 0.02 Heavy metal total Note 1, Mg/kg ≤ Lead (Pb) 90.0 Cadmium (Cd) 100.0 Chlorinated phenol (see attached) Recorded D) and o-phenyl phenol, Mg/kg ≤ Pentachlorophenol (PCP) 0.05 0.5 Tetrachlorophenol (TeCP total) 0.05 0.5 O-phenylphenol (OPP) 0.5 1.0 Organotin compounds, Mg/kg ≤ Tributyltin compounds (TBT) 0.5 1.0 Triphenyltin compounds (TPhT) 0.5 1.0 Dibutyltin compounds (DBT) 1.0 2.0 Dioctyltin compounds (DOT) 1.0 2.0 Chlorinated benzene and chlorinated toluene (see Appendix E) Mg/kg ≤ 1.0 Phthalates Note 2 (see Appendix F),% ≤ 0.1 Polycyclic Aromatic Hydrochloride Note 2 (PAHs) (See Appendix G), mg/kg Benzo [a] pyrene 0.5 1.0 Total 5 10.0 Perfluorinated compounds Note 3 (PFC) Perfluorooctanoic acid (PFOA), Mg/kg ≤ 0.05 0.1 Perfluorooctane sulfonylation (PFOS), μg/m2 ≤ 1.0 Residual surface activity Agent, mg/kg ≤ Octylphenol (OP), nonylphenol (NP), octylphenol polyoxyethylene Alkene (OPEO), nonyl Phenol polyoxyethylene ether (NPEO) total Dimethyl fumarate (DMF), mg/kg ≤ 0.1 Note 1. coated or coated textile products. Note 2. textile products containing plastic materials and coatings. Note 3. Applicable to coated textile products. 5.3 Product packaging requirements 5.3.1 Packaging materials Use recyclable and degradable materials. 5.3.2 Product packaging should be marked according to GB/T 18455. 6 test method 6.1 Technical contents 5.1.2 Detection of hazardous substances in coating agents shall be carried out in accordance with the method specified in HJ 2541. 6.2 Technical contents 5.1.3 Detection of volatile organic compounds in printing paste according to the method specified in GB/T 23986-2009. 6.3 Technical contents 5.2.2 The pH value in Table 2 shall be tested in accordance with the provisions of GB/T 7573-2009. 6.4 Technical contents 5.2.2 The detection of formaldehyde in Table 2 shall be carried out in accordance with the provisions of GB/T 2912.1-2009. 6.5 Technical content 5.2.2 The extraction of extractable heavy metals in Table 2 is carried out in accordance with the provisions of GB/T 17593-2006. 6.6 Technical content 5.2.2 Table 2 heavy metal lead, total cadmium detection in accordance with the provisions of GB/T 30157-2013 method. 6.7 Technical content 5.2.2 The detection of chlorinated phenol in Table 2 is carried out in accordance with the method specified in ISO /IEC 15144-1-2006. 6.8 Technical requirements 5.2.2 The detection of pentachlorophenol in Table 2 is carried out in accordance with the method specified in ISO /IEC 154414-2-2006. 6.9 Technical content 5.2.2 The detection of o-phenylphenol in Table 2 is carried out according to the method specified in GB/T 20386-2006. 6.10 Technical content 5.2.2 The detection of organotin compounds in Table 2 was carried out in accordance with the method specified in GB/T 20385-2006. 6.11 Technical content 5.2.2 The detection of chlorobenzene and chlorinated toluene in Table 2 is carried out according to the method specified in GB/T 20384-2006. 6.12 Technical content 5.2.2 The total amount of phthalate in Table 2 was tested according to the method specified in GB/T 20388-2006. 6.13 Technical content 5.2.2 The detection of PAHs in Table 2 was carried out in accordance with the method specified in GB/T 28189-2011. 6.14 Technical content 5.2.2 Table 2 in the octyl phenol, nonyl phenol detection in accordance with the provisions of GB/T 23972-2011 method. 6.15 Technical content 5.2.2 Table 2 in the octyl phenol polyoxyethylene ether, nonyl phenol polyoxyethylene ether in accordance with GB/T 23322-2009 Method. 6.16 Technical content 5.2.2 Determination of perfluorooctane sulfonyl compounds and perfluorooctanoic acid in Table 2 In accordance with SN/T 2842-2011 Method. 6.17 Technical content 5.2.2 The detection of dimethyl fumarate in Table 2 was carried out in accordance with the method specified in GB/T 28190-2011. 6.18 Other requirements in the technical content are verified by means of document review and on-site inspection. Appendix A (Normative) carcinogenic aromatic amines Chinese name English name 4-aminobiphenyl 4-Aminobiphenyl Benzidine Benzidine 4-Chloro-o-toluidine 4-Chloro-o-toluidine 2-naphthylamine 2-Naphthylamine O-azobenzene o-Aminoazotoluene 2-Amino-4-nitrotoluene 2-Amino-4-nitrotoluene P - Chloroaniline 2,4-diaminoanisole 2,4-Diaminoanisole 4,4'-diaminodiphenylmethane 4,4'-Diaminobiphenylmethane 3,3'-dichlorobenzidine 3,3'-Dichlorobenzidine 3,3'-dimethoxybenzidine 3,3'-Dimethoxybenzidine 3,3'-dimethylbenzidine 3,3'-Dimethylbenzidine 3,3'-Dimethyl-4,4'-diaminobiphenylmethane 3,3'-Dimethyl-4,4'-diaminobiphenylmethane 2-methoxy-5-methylaniline p-Cresidine/(p-Kresidine) 3,3'-dichloro-4,4'-diaminodiphenylmethane 4,4'-methylene-bis- (2-chloroaniline) 4,4'-diaminobiphenyl ether 4,4'-Oxydianiline 4,4'-diaminodiphenyl sulfide 4,4'-Thiodianiline O-methyl aniline o-Toluidine 2,4-diaminotoluene 2,4-Toluylendiamine 2,4,5-trimethylaniline 2,4,5-Trimethylaniline O-methyl anisole/2-methoxyaniline o-Anisidine/2-Methoxyanilin 2,4-dimethylaniline 2,4-Xylidine 2,6-dimethylaniline 2,6-Xylidine 4-aminoazobenzene 4-Aminoazobenzene Appendix B (Normative appendix) Prohibited use of carcinogenic dyes Chinese name English name CI Acid Red 26 CIAcid Red 26 CI Alkaline Red 9 CIBasic Red 9 CI alkaline violet 14 CIBasic Violet 14 CI Direct Black 38 CIDirect Black 38 CI Direct Blue 6 CIDirect Blue 6 CI Direct Red 28 CIDirect Red 28 CI Disperse Blue 1 CIDisperse Blue 1 CI Disperse Orange 11 CIDisperse Orange 11 CI Disperse Yellow 3 CIDisperse Yellow 3 Appendix C (Normative appendix) Prohibited use of sensitized disperse dyes Chinese name English name CI Disperse Blue 1 CIDisperse Blue 1 CI Dispersed Blue 3 CIDisperse Blue 3 CI Dispersed Blue 7 CIDisperse Blue 7 CI Disperse Blue 26 CIDisperse Blue 26 CI disperse blue 35 CIDisperse Blue 35 CI Disperse Blue 102 CIDisperse Blue 102 CI Disperse Blue 106 CIDisperse Blue 106 CI Disperse Blue 124 CIDisperse Blue 124 CI Disperse Brown 1 CIDisperse Brown 1 CI Disperse Orange 1 CIDisperse Orange 1 CI Disperse Orange 3 CIDisperse Orange 3 CI Disperse Orange 37 CIDisperse Orange 37 CI Disperse Orange 76 CIDisperse Orange 76 CI Disperse Red 1 CIDisperse Red 1 CI Disperse Red 11 CIDisperse Red 11 CI Scattered Red 17 CIDisperse Red 17 CI Disperse Yellow 1 CIDisperse Yellow 1 CI Disperse Yellow 3 CIDisperse Yellow 3 CI Disperse Yellow 9 CIDisperse Yellow 9 CI Disperse Yellow 39 CIDisperse Yellow 39 CI Disperse Yellow 49 CIDisperse Yellow 49 Appendix D (Normative appendix) Limit the use of chlorinated phenol Chinese name English name Pentachlorophenol Pentachlorophenol 2,3,5,6-tetrachlorophenol 2,3,5,6-Tetrachlorphenol 2,3,4,6-tetrachlorophenol 2,3,4,6-Tetrachlorphenol 2,3,4,5-tetrachlorophenol 2,3,4,5-Tetrachlorphenol Appendix E (Normative appendix) Limited use of chlorinated benzene and chlorinated toluene Chinese name English name Dichlorobenzenes Dichlorobenzenes Trichlorobenzene Trichlorobenzenes Tetrachlorobenzene Tetrachlorobenzenes Pentachlorobenzenes Pentachlorobenzenes Hexachlorobenzenes Chlorotoluene Chlorotoluene Dichlorotoluenes Trichlorotoluene Trichlorotoluenes Tetrachlorotoluene Tetrachlorotoluenes Pentachlorotoluene Pentachlorotoluene Appendix F (Normative appendix) Restricted use of phthalates Chinese name English name abbreviation Di-iso-nonylphthalate phthalate Di-iso-nonylphthalate Di-n-octylphthalate DNOP Di-(2-ethylhexy) phthalate DEHP Diisodecylphthalate DIDP Butylbenzylphthalate BBP Dibutylphthalate Dibutylphthalate Diisoctyl phthalate DIBP (C6-8 branched chain) alkyl phthalate Di-C6-8-branched Alkyphthalates DIHP Phthalic acid bis (C7-11 branched and linear) Alkyl esters Di-C7-11-branched Alkyphthalates DHNUP Di-n-hexylphthalate DHP Dimethoxyethyl phthalate Di- (2-methoxyethyl) - Phthalate DMEP Appendix G (Normative appendix) Restricted use of polycyclic aromatic hydrocarbons (PAHs) Chinese name English name Acenaphthene Acenaphtene 1,8-ethylidene naphenaphthylene Anthracene Benzo [a] anthracene Benzo [a] anthracene Benzo pyrene Benzo [a] pyrene Benzo [b] fluoranthene Benzo [b] fluoranthene Benzo [ghi] perylene Benzo [ghi] perylene Benzo [k] fluoranthene Benzo [k] fluoranthene Qu Chrysene Dibenz [a, h] anthracene Fluoranthene Fluoranthene Fluorene Fluorene Indene [1,2,3-cd] pyrene Indeno [1,2,3-cd] pyrene Naphthalene naphthalene Phenanthrene Pyrene Pyrene ......

BASIC DATA
Standard ID HJ 2546-2016 (HJ2546-2016)
Description (Translated English) Technical requirement for environmental labeling products Textile products
Sector / Industry Environmental Protection Industry Standard
Classification of Chinese Standard Z04
Word Count Estimation 15,145
Date of Issue 2016-11-14
Date of Implementation 2017-01-01
Older Standard (superseded by this standard) HJ/T 309-2006; HJ/T 307-2006
Regulation (derived from) Ministry of Environmental Protection Notice No.696 of 2016