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HJ 2546-2016 (HJ2546-2016)

Chinese standards (related to): 'HJ 2546-2016'
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HJ 2546-2016English349 Add to Cart 3 days Technical requirement for environmental labeling products Textile products HJ 2546-2016 Valid HJ 2546-2016


   
BASIC DATA
Standard ID HJ 2546-2016 (HJ2546-2016)
Description (Translated English) Technical requirement for environmental labeling products Textile products
Sector / Industry Environmental Protection Industry Standard
Classification of Chinese Standard Z04
Word Count Estimation 15,145
Date of Issue 2016-11-14
Date of Implementation 2017-01-01
Older Standard (superseded by this standard) HJ/T 309-2006; HJ/T 307-2006
Regulation (derived from) Ministry of Environmental Protection Notice No.696 of 2016


HJ 2546-2016: PDF in English
HJ 2546-2016
(Environmental labeling products Technical requirements Textile products)
National Environmental Protection Standard of the People 's Republic of China
Replacing HJ/T 307-2006, HJ/T 309-2006
Environmental labeling products Technical requirements Textile products
Technical requirement for environmental labeling products
Textile products
2016-11-14 release
2017-01-01 Implementation
Ministry of Environmental Protection released
Directory
Preface ..II
1 Scope of application 1
2 normative reference document 1
3 terms and definitions
4 basic requirements 2
5 technical content 2
6 test method 4
Appendix A (normative) carcinogenic aromatic amines
Appendix B (normative) Prohibited use of carcinogenic dyes 7
Appendix C (normative) prohibits the use of sensitized disperse dyes
Appendix D (normative) Restricted use of chlorinated phenol 9
Annex E (normative) restrictions on the use of chlorobenzene and chlorinated toluene 9
Appendix F (normative) Restricted use of phthalate 10
Appendix G (normative) Restricted use of PAHs 11
Preface
To implement the "People's Republic of China Environmental Protection Law" to reduce the textile products in the production and use of the environment and human health
Influence, protect the environment, develop this standard.
This standard on the production of textile products, products, toxic and hazardous substances and product packaging and other requirements.
This standard will be "environmental labeling products technical requirements eco-textiles" (HJ/T 307-2006) and "environmental labeling products technology
(HJ/T 309-2006), the main changes are as follows.
- Adjusted the standard name and scope of application;
- Increased requirements for baking of surfactants and asbestos fibers in raw materials
- Increased restrictions on the use of coating finishing agents and hazardous substances in the coloring process used in the production process;
- Added dyes, insecticides, flame retardant finishing agents, chlorinated benzene and chlorinated toluene, phthalates, organotin compounds
Disable category
- Adjusted formaldehyde requirements;
- Increased total lead, total cadmium content, polycyclic aromatic hydrocarbons, perfluorinated compounds, residual surfactants, fumaric acid di
Methyl ester requirements;
- increased product packaging requirements;
- Removes the requirements of antibacterial finishing agents, color fastness, volatile substances, metal sharp objects;
- Adjust the inspection method.
This standard is organized by the Ministry of Environmental Protection Science and Technology Standards Division.
The main drafting unit of this standard. Environmental Development Department of Environmental Protection, Textile Industry Southern Science and Technology Testing Center, Jiangsu Entry and Exit Inspection
Inspection and Quarantine Bureau of textile industry product testing center, reputation standard detection (Shenzhen) Co., Ltd., Guangdong Esquel Textile Co., Ltd., Zhejiang hi
Po Silk Technology Co., Ltd., Zhejiang Furun Printing and Dyeing Co., Ltd., Huzhou Zhenbei Cashmere Products Co.,
The environmental protection department of this standard approved on November 14,.2016.
This standard has been implemented since January 1,.2017.
This standard is explained by the Ministry of Environmental Protection.
This standard replaced the previous version of the standard release.
- HJ/T 307-2006, HJ BZ 30-2000, HJ BZ 30-1998, HJ BZ 005-1994;
- HJ/T 309-2006, HJ BZ 11-1996.
Environmental labeling products Technical requirements Textile products
1 Scope of application
This standard specifies the terms and definitions, basic requirements, technical contents and test methods for textile product environmental labeling products.
This standard applies to all types of textile products.
2 normative reference documents
The contents of this standard refer to the terms of the following documents. For undated references, the valid version applies to this standard.
Technical specification for basic safety of national textile products GB 18401-2010
Technical code for safety of infant and children 's textile products GB 31701-2015
GB/T 2912.1-2009 Textiles - Determination of formaldehyde - Part 1. Free hydrolysis of formaldehyde (water extraction)
Textiles - Determination of pH value of aqueous extract
Textiles - Determination of heavy metals GB/T 17593-2006
GB/T 18414.1-2006 Textiles - Determination of chlorinated phenol - Part 1. Gas chromatography - mass spectrometry
Textiles - Determination of chlorophenol - Part 2. Gas chromatographic method GB/T 18414.2-2006
GB/T 18455 Packaging Recycling Mark
Technical requirements for eco - textiles GB/T 18885
Textiles - Determination of benzene and chlorinated toluene residues GB/T 20384-2006
Textiles - Determination of organotin compounds GB/T 20385-2006
Textiles - Determination of o - phenylphenol GB/T 20386-2006
Textiles - Determination of phthalate esters GB/T 20388-2006
Textiles - Determination of surface active agent - Alkylphenol ethoxylates GB/T 23322-2009
GB/T 23972-2011 Determination of alkylphenols and alkylphenol polyoxyethylene ethers in textile dyeing and finishing aids High performance liquid chromatography /
Mass spectrometry
Paints and varnishes - Determination of volatile organic compounds (VOC) content - Gas chromatographic method GB/T 23986-2009 GB/T 23986-2009
Textiles - Determination of polycyclic aromatic hydrocarbons (PAHs) GB/T 28189-2011
GB/T 28190-2011 Textiles - Determination of dimethyl fumarate
Textiles - Determination of total lead and total cadmium content GB/T 30157-2013
HJ 2541 Environmental labeling products Technical requirements Adhesives
HJ/T 185-2006 Cleaner Production Standard Textile (Cotton Printing and Dyeing)
HJ/T 359-2007 Clean production standard Chemical fiber industry (polyester)
HJ/T 429-2008 Clean production standard Chemical fiber industry (spandex)
SN/T 2842-2011 Determination of perfluorooctane sulfonate and perfluorooctanoic acid in textiles by liquid chromatography tandem mass spectrometry
3 terms and definitions
The following terms and definitions apply to this standard.
3.1 textile products
To natural fiber and/or chemical fiber as the main raw material, by spinning, weaving, dyeing and other processing technology or by sewing, composite and other processes made
Products such as yarns, fabrics and their finished products. (GB 18401-2010)
3.2 Infant Textile Products textile products for infants
The age of 36 months and below the infants wear or use of textile products. (GB 18401-2010)
3.3 children's textile products textile products for children
Textiles for children aged 3 years and older and children 14 years of age or older Note 1. (GB 31701-2015)
Note 1. Generally apply to the height of 100cm or more, 155cm and below girls or 160cm and below the boys wearing or use the textile
Products can be used as children's textile products. Among them, 130cm and below children can be seen as children under the age of 7 clothing. (GB
31701-2015)
3.4 Textile products with direct contact with skin
In the wearing and use of the product, most of the area directly with the human skin contact with the textile products. (GB 18401-2010)
3.5 Textile products that are not directly exposed to skin textile products without direct contact to skin
When dressed and used, the product is not directly in contact with human skin, or only a small area of direct contact with the human skin in contact with the textile
product. (GB 18401-2010)
3.6 Decorative textile products Decorative textile products
For decorative products (such as tablecloths, wall covering, curtains, carpets, etc.).
4 basic requirements
4.1 product quality, safety performance should meet the requirements of the corresponding standards.
4.2 The pollutant discharge of the product manufacturer shall conform to the pollutant discharge standard stipulated by the state or local.
4.3 production process should strengthen the clean production, which spandex, polyester and cotton printing and dyeing enterprises should be clean production level HJ/T
429-2008, HJ/T 359-2007, HJ/T 185-2006 Secondary standard requirements.
5 technical content
5.1 Requirements for the production process
5.1.1 The substances listed in Table 1 are not used in the production of textile products.
Table 1 Prohibited substances used in the production of textile products
Category Prohibited substances used in the production process
dye
Can be decomposed carcinogenic aromatic amine azo dyes (carcinogenic aromatic amine see Appendix A), carcinogenic dye (see attached
Recorded B), sensitizing disperse dyes (see Appendix C)
Flame retardant finishing agent
Polybrominated biphenyls (PBB), tris- (2,3-dibromopropyl) -phosphate (TRIS), triethyl phosphonoacetate
(TEPA), pentabromodiphenyl ether (PeBDE), octabromodiphenyl ether (OcBDE), decabromodiphenyl ether
(HBCDD), short chain chlorinated paraffins (SCCP), tris (2-
Carboxyethyl) phosphine (TCEP)
Surfactant
Alkylphenol polyoxyethylene ethers (APEOs), nitrilotriacetic acid (NTA), bis (hydrogenated tallow alkyl)
Dimethyl ammonium chloride (DTDMAC), distearyl dimethyl ammonium chloride (DSDMAC), di
Butter) dimethyl ammonium chloride (DHTDMAC), ethylenediamine tetraacetate (EDTA) and diethyl
Triamine Pentaacetate (DTPA)
Fiber asbestos
5.1.2 Hazardous substances in solvent-based coating agents shall meet the requirements of the corresponding categories in the HJ 2541 standard.
5.1.3 The volatile organic compounds (VOCs) in the printing paste should be no more than 5%.
5.2 Requirements for Hazardous Substances in Products
5.2.1 The total amount of pesticide in natural textile products should meet the requirements of GB/T 18885.
5.2.2 The limit of hazardous substances in textile products shall meet the requirements of Table 2.
Table 2 Restrictions on Hazardous Substances in Textile Products
classification
Test items
Infant textile production
Children and direct contact
Skin textile products
Non-direct contact with skin
Skin and decorative spinning
Woven products
PH 4.0-7.5 4.0-7.5 4.0-9.0
Formaldehyde, mg/kg ≤ Not detected 30.0 75.0
Extractable
Heavy metals,
Mg/kg ≤
Arsenic (As) 0.2 1.0
Lead (Pb) 0.2 1.0
Chromium (Cr) 1.0 2.0
Co (Co) 1.0 4.0
Copper (Cu) 25.0 50.0
Nickel (Ni) 1.0 4.0
Chromium (Cr) (Ⅵ) may not be detected
Cadmium (Cd) 0.1
Antimony (Sb) 30.0
Mercury (Hg) 0.02
Heavy metal total Note 1,
Mg/kg ≤
Lead (Pb) 90.0
Cadmium (Cd) 100.0
Chlorinated phenol (see attached)
Recorded D) and o-phenyl
phenol,
Mg/kg ≤
Pentachlorophenol (PCP) 0.05 0.5
Tetrachlorophenol (TeCP total) 0.05 0.5
O-phenylphenol (OPP) 0.5 1.0
Organotin compounds,
Mg/kg ≤
Tributyltin compounds
(TBT)
0.5 1.0
Triphenyltin compounds
(TPhT)
0.5 1.0
Dibutyltin compounds
(DBT)
1.0 2.0
Dioctyltin compounds
(DOT)
1.0 2.0
Chlorinated benzene and chlorinated toluene (see Appendix E)
Mg/kg ≤ 1.0
Phthalates Note 2 (see Appendix F),% ≤ 0.1
Polycyclic Aromatic Hydrochloride Note 2 (PAHs)
(See Appendix G), mg/kg
Benzo [a] pyrene 0.5 1.0
Total 5 10.0
Perfluorinated compounds Note 3
(PFC)
Perfluorooctanoic acid (PFOA),
Mg/kg ≤ 0.05 0.1
Perfluorooctane sulfonylation
(PFOS), μg/m2 ≤ 1.0
Residual surface activity
Agent, mg/kg ≤
Octylphenol (OP), nonylphenol
(NP), octylphenol polyoxyethylene
Alkene (OPEO), nonyl
Phenol polyoxyethylene ether
(NPEO) total
Dimethyl fumarate (DMF), mg/kg ≤ 0.1
Note 1. coated or coated textile products.
Note 2. textile products containing plastic materials and coatings.
Note 3. Applicable to coated textile products.
5.3 Product packaging requirements
5.3.1 Packaging materials Use recyclable and degradable materials.
5.3.2 Product packaging should be marked according to GB/T 18455.
6 test method
6.1 Technical contents 5.1.2 Detection of hazardous substances in coating agents shall be carried out in accordance with the method specified in HJ 2541.
6.2 Technical contents 5.1.3 Detection of volatile organic compounds in printing paste according to the method specified in GB/T 23986-2009.
6.3 Technical contents 5.2.2 The pH value in Table 2 shall be tested in accordance with the provisions of GB/T 7573-2009.
6.4 Technical contents 5.2.2 The detection of formaldehyde in Table 2 shall be carried out in accordance with the provisions of GB/T 2912.1-2009.
6.5 Technical content 5.2.2 The extraction of extractable heavy metals in Table 2 is carried out in accordance with the provisions of GB/T 17593-2006.
6.6 Technical content 5.2.2 Table 2 heavy metal lead, total cadmium detection in accordance with the provisions of GB/T 30157-2013 method.
6.7 Technical content 5.2.2 The detection of chlorinated phenol in Table 2 is carried out in accordance with the method specified in ISO /IEC 15144-1-2006.
6.8 Technical requirements 5.2.2 The detection of pentachlorophenol in Table 2 is carried out in accordance with the method specified in ISO /IEC 154414-2-2006.
6.9 Technical content 5.2.2 The detection of o-phenylphenol in Table 2 is carried out according to the method specified in GB/T 20386-2006.
6.10 Technical content 5.2.2 The detection of organotin compounds in Table 2 was carried out in accordance with the method specified in GB/T 20385-2006.
6.11 Technical content 5.2.2 The detection of chlorobenzene and chlorinated toluene in Table 2 is carried out according to the method specified in GB/T 20384-2006.
6.12 Technical content 5.2.2 The total amount of phthalate in Table 2 was tested according to the method specified in GB/T 20388-2006.
6.13 Technical content 5.2.2 The detection of PAHs in Table 2 was carried out in accordance with the method specified in GB/T 28189-2011.
6.14 Technical content 5.2.2 Table 2 in the octyl phenol, nonyl phenol detection in accordance with the provisions of GB/T 23972-2011 method.
6.15 Technical content 5.2.2 Table 2 in the octyl phenol polyoxyethylene ether, nonyl phenol polyoxyethylene ether in accordance with GB/T 23322-2009
Method.
6.16 Technical content 5.2.2 Determination of perfluorooctane sulfonyl compounds and perfluorooctanoic acid in Table 2 In accordance with SN/T 2842-2011
Method.
6.17 Technical content 5.2.2 The detection of dimethyl fumarate in Table 2 was carried out in accordance with the method specified in GB/T 28190-2011.
6.18 Other requirements in the technical content are verified by means of document review and on-site inspection.
Appendix A
(Normative) carcinogenic aromatic amines
Chinese name English name
4-aminobiphenyl 4-Aminobiphenyl
Benzidine Benzidine
4-Chloro-o-toluidine 4-Chloro-o-toluidine
2-naphthylamine 2-Naphthylamine
O-azobenzene o-Aminoazotoluene
2-Amino-4-nitrotoluene 2-Amino-4-nitrotoluene
P - Chloroaniline
2,4-diaminoanisole 2,4-Diaminoanisole
4,4'-diaminodiphenylmethane 4,4'-Diaminobiphenylmethane
3,3'-dichlorobenzidine 3,3'-Dichlorobenzidine
3,3'-dimethoxybenzidine 3,3'-Dimethoxybenzidine
3,3'-dimethylbenzidine 3,3'-Dimethylbenzidine
3,3'-Dimethyl-4,4'-diaminobiphenylmethane 3,3'-Dimethyl-4,4'-diaminobiphenylmethane
2-methoxy-5-methylaniline p-Cresidine/(p-Kresidine)
3,3'-dichloro-4,4'-diaminodiphenylmethane 4,4'-methylene-bis- (2-chloroaniline)
4,4'-diaminobiphenyl ether 4,4'-Oxydianiline
4,4'-diaminodiphenyl sulfide 4,4'-Thiodianiline
O-methyl aniline o-Toluidine
2,4-diaminotoluene 2,4-Toluylendiamine
2,4,5-trimethylaniline 2,4,5-Trimethylaniline
O-methyl anisole/2-methoxyaniline o-Anisidine/2-Methoxyanilin
2,4-dimethylaniline 2,4-Xylidine
2,6-dimethylaniline 2,6-Xylidine
4-aminoazobenzene 4-Aminoazobenzene
Appendix B
(Normative appendix)
Prohibited use of carcinogenic dyes
Chinese name English name
CI Acid Red 26 CIAcid Red 26
CI Alkaline Red 9 CIBasic Red 9
CI alkaline violet 14 CIBasic Violet 14
CI Direct Black 38 CIDirect Black 38
CI Direct Blue 6 CIDirect Blue 6
CI Direct Red 28 CIDirect Red 28
CI Disperse Blue 1 CIDisperse Blue 1
CI Disperse Orange 11 CIDisperse Orange 11
CI Disperse Yellow 3 CIDisperse Yellow 3
Appendix C
(Normative appendix)
Prohibited use of sensitized disperse dyes
Chinese name English name
CI Disperse Blue 1 CIDisperse Blue 1
CI Dispersed Blue 3 CIDisperse Blue 3
CI Dispersed Blue 7 CIDisperse Blue 7
CI Disperse Blue 26 CIDisperse Blue 26
CI disperse blue 35 CIDisperse Blue 35
CI Disperse Blue 102 CIDisperse Blue 102
CI Disperse Blue 106 CIDisperse Blue 106
CI Disperse Blue 124 CIDisperse Blue 124
CI Disperse Brown 1 CIDisperse Brown 1
CI Disperse Orange 1 CIDisperse Orange 1
CI Disperse Orange 3 CIDisperse Orange 3
CI Disperse Orange 37 CIDisperse Orange 37
CI Disperse Orange 76 CIDisperse Orange 76
CI Disperse Red 1 CIDisperse Red 1
CI Disperse Red 11 CIDisperse Red 11
CI Scattered Red 17 CIDisperse Red 17
CI Disperse Yellow 1 CIDisperse Yellow 1
CI Disperse Yellow 3 CIDisperse Yellow 3
CI Disperse Yellow 9 CIDisperse Yellow 9
CI Disperse Yellow 39 CIDisperse Yellow 39
CI Disperse Yellow 49 CIDisperse Yellow 49
Appendix D
(Normative appendix)
Limit the use of chlorinated phenol
Chinese name English name
Pentachlorophenol Pentachlorophenol
2,3,5,6-tetrachlorophenol 2,3,5,6-Tetrachlorphenol
2,3,4,6-tetrachlorophenol 2,3,4,6-Tetrachlorphenol
2,3,4,5-tetrachlorophenol 2,3,4,5-Tetrachlorphenol
Appendix E
(Normative appendix)
Limited use of chlorinated benzene and chlorinated toluene
Chinese name English name
Dichlorobenzenes Dichlorobenzenes
Trichlorobenzene Trichlorobenzenes
Tetrachlorobenzene Tetrachlorobenzenes
Pentachlorobenzenes Pentachlorobenzenes
Hexachlorobenzenes
Chlorotoluene Chlorotoluene
Dichlorotoluenes
Trichlorotoluene Trichlorotoluenes
Tetrachlorotoluene Tetrachlorotoluenes
Pentachlorotoluene Pentachlorotoluene
Appendix F
(Normative appendix)
Restricted use of phthalates
Chinese name English name abbreviation
Di-iso-nonylphthalate phthalate Di-iso-nonylphthalate
Di-n-octylphthalate DNOP
Di-(2-ethylhexy) phthalate DEHP
Diisodecylphthalate DIDP
Butylbenzylphthalate BBP
Dibutylphthalate Dibutylphthalate
Diisoctyl phthalate DIBP
(C6-8 branched chain) alkyl phthalate
Di-C6-8-branched
Alkyphthalates
DIHP
Phthalic acid bis (C7-11 branched and linear)
Alkyl esters
Di-C7-11-branched
Alkyphthalates
DHNUP
Di-n-hexylphthalate DH......