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TSG R0006-2014 English PDF

TSG R0006-2014_English: PDF (TSGR0006-2014)
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BASIC DATA
Standard ID TSG R0006-2014 (TSGR0006-2014)
Description (Translated English) Supervision regulation on safety technology for gas cylinder
Sector / Industry Special Equipment Industry Standard
Classification of Chinese Standard J74
Classification of International Standard 23.020.30
Word Count Estimation 56,538
Date of Issue 2014/9/5
Date of Implementation 2015/1/1
Older Standard (superseded by this standard) ZBFGH 55-2000; ZBFGH 53-1993
Drafting Organization Dalian Institute of Boiler and Pressure Vessel Inspection
Administrative Organization China Special Equipment Inspection and Research Institute
Regulation (derived from) National AQSIQ 2014 No. 98
Issuing agency(ies) Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Summary This Standard applies to normal ambient temperature (-40��C ~ 60��C, Note 1-1) for use nominal volume of 0.4L ~ 3000 L, nominal working pressure of 0.2MPa ~ 35MPa (gauge pressure, the same below) and the pressure and the mixed gas with a liquid volume of th


TSG R0006-2014 TECHNICAL SPECIFICATION FOR SAFETY OF SPECIAL EQUIPMENT Supervision regulation on safety technology for gas cylinder ISSUED ON: SEPTEMBER 05, 2014 IMPLEMENTED ON: JANUARY 01, 2015 Issued by: General Administration of Quality Supervision, Inspection and Quarantine of PRC Table of Contents Foreword ... 3  1 General ... 5  2 Materials ... 13  3 Design ... 17  4 Manufacture ... 24  5 Accessories of gas cylinders ... 29  6 Filling and use ... 35  7 Periodic inspection ... 42  8 Supplementary ... 47  Appendix A Gas cylinder’s variety, variety code, corresponding product standard ... 48  Appendix B Gas cylinder’s mark ... 50  Appendix C Saturated vapor pressure, filling factor, physical properties of commonly used cylindered gases ... 59  Appendix D Periodic inspection report of gas cylinder ... 65  Appendix E Catalog of national standards for gas cylinder ... 67  Relevant regulations and specifications ... 69  Foreword In April 2008, the Special Equipment Safety Supervision Bureau (hereinafter referred to as the Special Equipment Bureau) of the General Administration of Quality Supervision, Inspection and Quarantine (hereinafter referred to as the AQSIQ) issued the task book for drafting the “Supervision regulation on safety technology for gas cylinder (hereinafter referred to as “Regulation”)” to the China Special Equipment Inspection and Research Institute (hereinafter referred to as the China Special Inspection Institute). In May 2008, the China Special Inspection Institute organized relevant experts to set up a drafting group and held the first working meeting in Beijing, to discuss the principles, key contents, main issues, structure (chapter) framework for the drafting of the Regulations, made specific work division on the drafting work, established a time schedule for the drafting work. In October 2008 and March 2009, the drafting group held the second and third drafting work meetings in Beijing, to discuss and revise and form the draft of “Regulation” for comments. In September 2010, the drafting group held the fourth working meeting in Zhejiang Shangyu, to make corresponding modifications of the draft of “Regulation” for comments. In April 2011, after reviewing the draft for comments, the Special Equipment Bureau solicited for comments online in the form of ZJTH [2011] No.19 documents. In September 2011, according to the solicited opinions, the drafting group held its fifth working meeting in Beijing, formed a revision opinion on the draft of “Regulation” for comments. In December 2011, the drafting group revised and formed the “Regulation” for review in accordance with the spirit of the fifth work meeting. In May 2012, the Special Equipment Bureau submitted the draft for review to the Special Equipment Safety Technical Committee of the General Administration of Quality Supervision, Inspection and Quarantine for review. The drafting group revised the draft to form a draft for approval according to the review opinions. On September 5, 2014, the “Regulation” was approved by the General Administration of Quality Supervision, Inspection and Quarantine for release. The basic principles of the drafting of this “Regulation” are that, according to the “Law on Safety of Special Equipment” and “Provisions on Safety Supervision of Special Equipment”, on the basis of fully absorbing and combining the actual situation and experience of safety supervision of gas cylinder for many years, in order to strengthen the safety supervision of gas cylinder, ensuring the safe use of gas cylinders, promoting the development of the national economy, protecting the safety of people and property, it establishes specific requirements for the safety supervision of gas cylinder in such links as material, design, manufacturing, gas cylinder’s accessories, filling and use, periodic inspections. The main drafting organizations and personnel of this Regulation are as follows: Dalian Boiler and Pressure Vessel Inspection and Research Institute: Hu Jun, Han Bing Capital University of Economics and Business: Wu Yuesang Beijing Tianhai Industry Co., Ltd.: Zhang Baoguo National Gas Cylinder Standardization Technical Committee: Huang Qianghua, Wu Yan, Wu Hong, Liu Shouzheng China Special Equipment Inspection and Research Institute: Bo Ke, Liang Lin Shanghai Special Equipment Supervisory inspection Technology Research Institute: Sun Li Shanghai Quality and Technical Supervision Bureau: Tan Jiuke Sichuan Bureau of Quality and Technical Supervision: Liao Yang Huizhou Quality and Technical Supervision Bureau: Pan Xianghua Zhejiang Jindun Pressure Vessel Co., Ltd.: Ma Xiakang, Yin Xieping Zhejiang University Institute of Chemical Machinery: Zheng Jinyang Shijiazhuang Anruike Gas Machinery Co., Ltd.: Wang Hongxia Supervision regulation on safety technology for gas cylinder 1 General 1.1 Purpose In order to ensure the safety of gas cylinders, protect the safety of people and property, promote the development of the national economy, this Regulation is hereby formulated in accordance with the “Law on Safety of Special Equipment” and “Provisions on Safety Supervision of Special Equipment”. 1.2 Scope of application This procedure is applicable to the seamless gas cylinders, welded gas cylinders, welded insulated gas cylinders, wound gas cylinders, gas cylinders filled with fillers, gas cylinder accessories which is used at a normal ambient temperature of (-40°C ~ 60°C, note 1-1), nominal volume of 0.4 L ~ 3000 L, nominal working pressure of 0.2 MPa ~ 35 MPa (gauge pressure, the same below), has a product of pressure multiplied by volume of more than or equal to 1.0 MPa • L, contains compressed gas, high (low) pressure liquefied gas, low-temperature liquefied gas, dissolved gas, adsorbed gas, liquid with a normal boiling point of equal to or less than 60°C, mixed gas (two or more than two kinds of gases). The materials, design, manufacture of gas cylinders for fire extinguishers, large- volume gas cylinders used for long tube trailers and tube bundle containers, or large-volume gas cylinders for electronic gas are in accordance with this Regulation. The main gas cylinder varieties, variety codes, corresponding product standards as covered by this Regulation are as shown in Appendix A. Note 1-1: The ambient temperature range of gas cylinders for vehicles and fire extinguishers shall be in accordance with the relevant standards. 1.3 Special provisions on the scope of application The cylinder accessories in the scope of application in clause 1.2 of this Regulation shall, in addition to complying with this Regulation, also comply with the provisions of the “Gas cylinder appurtenances safety and technical supervision regulation” (TSG RF001). The gas cylinders for vehicles (Note 1-2) shall, in addition to complying with this Regulation, also comply with the provisions of the “Gas cylinders safety and technical supervision regulation for vehicles” (TSG R0009). Note 1-2: The gas cylinders for vehicles as covered in this Regulation refer to the gas cylinders used to contain vehicle fuels (such as compressed natural gas, liquefied natural gas, hydrogen, liquefied petroleum gas, liquefied dimethyl ether, etc.). 1.4 Scope of non-application This Regulation does not apply to gas cylinders for fire extinguishers that are only subjected to transient pressure during firefighting and are not subject to pressure during storage, fixed-use cylinder-type pressure vessels, gas cylinders for military equipment, nuclear facilities, aerospace vehicles, railway locomotives, offshore installations and ships, special equipment for civil airports. 1.5 Relationship with standards and management systems This Regulation specifies the basic safety requirements for gas cylinders. The technical standards and management systems for gas cylinders shall comply with the provisions of this Regulation. The design, manufacture, filling, inspection of gas cylinders (including gas cylinder’s accessories) shall comply with the corresponding standards as specified in this Regulation. When there are no corresponding national standards, industrial standards, or the case where it is beyond the current national standards and industrial standards due to the adoption of new materials, new technologies, new processes, it shall establish enterprise standards. Enterprise standards shall be formulated by using or referring to international standards (or advanced foreign standards); comply with the requirements of Chinese laws and regulations and safety technical specifications; fully seek the opinions of relevant competent authorities and relevant organizations and institutions such as manufacturing, filling, inspection, use. The content of the enterprise standard beyond the provisions of this Regulation shall be subject to the standard review by the national gas cylinder standardization technical organization. Meanwhile it shall follow the Appendix A of this Regulation to define the variety code of the gas cylinder. 1.6 Special treatment for inconsistency with this Regulation When the gas cylinders which use new materials, new technologies, new processes, or otherwise has special requirements for use, are inconsistent with the requirements of this Regulation, the manufacturing organization shall report to the AQSIQ. The reporting data includes at least the basis, data, results of relevant design, research, test, as well as the reviewed enterprise standards and their type test reports. The AQSIQ entrusts relevant professional and technical institutions to conduct technical review. Only after the results of the review are approved by the AQSIQ, it allows to formally put into production and use. The product standards on which the product is manufactured and type tested shall comply with the provisions of 1.5 of this Regulation. 1.7 Identification of design document and type test Cylinder products shall, according to the requirements of “Gas Cylinder Design Documents Appraisal Regulation” (TSG R1003) and “Regulation for Type Test of Gas Cylinders” (TSG R7002), be subjected to identification of design documents of gas cylinder products and type test. After being qualified, the design documents can be used for manufacturing. For the gas cylinder’s accessories as configured for the gas cylinder, if there is requirements in the safety technical specifications and the corresponding standards, it shall first be subjected to the type test of the accessories, then the gas cylinder. 1.8 Imported gas cylinder The imported gas cylinders shall, in addition to complying with the relevant provisions on the inspection of import and export commodities, also meet the requirements of this clause. 1.8.1 Manufacturing license The overseas manufacturing organization of the imported gas cylinder shall meet the requirements of 1.7 of this Regulation and obtain the corresponding manufacturing license for special equipment in China. 1.8.2 Specifications and corresponding standards for design and manufacture All types of imported gas cylinders used in China shall meet the following requirements: (1) Design and manufacture comply with China's safety technical specifications; (2) For gas cylinder products without Chinese national standards, or otherwise the scope of application and technical requirements of the standards used differ from the Chinese national standards, the gas cylinder product’s standards shall be evaluated by the relevant professional technical institutions as commissioned by the AQSIQ. 1.8.3 Supervisory inspection of safety performance of imported gas cylinders The imported gas cylinders shall be subject to the supervisory inspection of safety performance by the special equipment inspection agency (hereinafter referred to as the supervisory inspection agency) with the supervisory inspection qualifications, with inspection reports. The standards on which the inspections are based shall comply with the provisions of 1.8.2 of this Regulation, of which the manufacturing mark, exit-factory information and documents of the imported gas cylinder shall also comply with the provisions of 1.14.1 and 4.10 of this Regulation. 1.8.4 Temporary imported gas cylinders Temporary imported gas cylinders refer to cylinders as imported domestically, filled, then exported overseas, or otherwise the gas cylinders as filled overseas, imported domestically, then exported to the overseas manufacturing enterprise after the gas in the cylinder is exhausted. It shall comply with the following requirements: (1) For organizations that are temporarily importing gas cylinders, it is necessary to provide the safety performance certificate as issued by the inspection agency which is approved officially by the country (or region) wherein the property right of the gas cylinder is located to the supervisory- inspection institute of the imported location; (2) The supervisory inspection agency will inspect the safety performance of the temporarily imported gas cylinders and issue the inspection report. For the gas cylinders which require repeated entry but cannot be tested for safety performance at the time of entry, they shall, after the gas in the cylinder is exhausted, be subjected to the inspection of safety performance. For gas cylinders that cannot be internally inspected due to gas characteristics, etc., the importing organization shall provide the valid inspection certificate as issued by the inspection agency of the country (or region) where the gas cylinder’s property rights are located, and only after confirmation by the supervisory inspection agency, it can only perform the appearance inspection and determination of wall thickness, with corresponding inspection reports. Gas cylinders that fail in the inspection (or appearance inspection, determination of wall thickness) shall not be used in China; (3) The gas cylinders which are in the validity period of the safety performance inspection report as issued by the supervisory inspection agency may not be tested for safety performance when leaving the country or re-entry; (4) For gas cylinders that have only undergone appearance inspection and determination of wall thickness, in case of re-entry, it shall follow the requirements of item (2) of this clause to perform the inspection of safety performance or appearance inspection and determination of wall thickness; (5) Organizations involved in the temporary import of gas cylinders shall establish temporary archives of imported gas cylinders. 1.9 Exported back gas cylinder Where the exported cylinder is returned back to China for use, its manufacturing organization shall obtain the corresponding special equipment manufacturing permit in China, meanwhile meet the requirements of the standard review, identification of design documents of gas cylinder, type test of the imported gas cylinders in clause 1.5 and 1.8 of this Regulation. 1.10 Cylindered gas medium Cylindered gas medium is divided into the following types: (1) Compressed gas: It refers to a gas that is completely gaseous after being pressurized at -50°C, including a gas which has a critical temperature (Tc) lower than or equal to -50°C, which is also called a permanent gas; (2) High (low) pressure liquefied gas: It refers to a gas that is partially liquid after pressurization at a temperature higher than -50°C, including high- pressure liquefied gas which has a critical temperature (Tc) of -50°C ~ 65°C, as well as low-pressure liquefied gas which has a critical temperature (Tc) of above 65°C; (3) Low-temperature liquefied gas: It refers to a gas that is partially liquid due to cryogenic low-temperature during transportation. Those which has a critical temperature (Tc) of generally lower than or equal to -50°C are also known as cryogenic liquefied gas or refrigerated liquefied gas; (4) Dissolved gas: It refers to the gas that dissolves in a solvent under pressure; (5) Adsorbed gas: It refers to the gas that is adsorbed to the adsorbent under pressure. 1.11 Nominal working pressure of gas cylinder (1) The nominal working pressure of a gas cylinder which contains compressed gas refers to the defined (charging) pressure when the gas in the cylinder reaches a completely uniform state at the reference temperature (20°C); (2) The nominal working pressure of a gas cylinder which contains liquefied gas refers to the upper limit of the gas pressure in the cylinder at a temperature of 60°C; (3) The nominal working pressure of a gas cylinder which contains dissolved gas refers to the standing pressure (at 15°C) of the gas in the gas cylinder under chemical, thermal and diffusion equilibrium conditions; (4) The nominal working pressure of the welded insulated gas cylinder refers to the highest pressure that can be reached in the gas phase at the top of the liner under normal working conditions of the gas cylinder; (5) The nominal working pressure of the gas cylinder which contains liquids with a standard boiling point of equal to or lower than 60°C and mixed gas shall be as specified by the relevant standards. The selection of the nominal working pressure of the gas cylinder shall be in accordance with the provisions of 3.6 of this Regulation. 1.12 Classification of cylinders 1.12.1 Classification by nominal working pressure Gas cylinders are divided into high-pressure gas cylinders and low-pressure gas cylinders according to the nominal working pressure: (1) High-pressure gas cylinder refers to a gas cylinder which has a nominal working pressure of more than or equal to 10 MPa; (2) Low-pressure gas cylinder refers to a gas cylinder which has a nominal working pressure of less than 10 MPa. 1.12.2 Classification by nominal volume Gas cylinders are divided into small-volume, medium-volume, large-volume cylinders by the nominal volume: (1) Small-volume gas cylinder refers to a gas cylinder which has a nominal volume is less than or equal to 12 L; (2) Medium-volume gas cylinder refers to a gas cylinder which has a nominal volume of more than 12 L and less than or equal to 150 L; (3) Large-volume gas cylinder refers to a gas cylinder which has a nominal volume of more than 150 L. 1.13 Special requirements for gas cylinder Gas cylinders which contain a single gas must be dedicated. It is only allowed to be filled with the gas consistent with the manufacturing mark. It shall neither change the gas cylinder’s manufacturing mark and its use, nor mix other gases or add additives. The gas cylinder which contains the mixed gas must be filled with the mixed gas of the same characteristics (Note 1-3), according to the gas characteristics as determined based on the gas cylinder’s mark. It is not allowed to modify a single gas or a mixed gas of different characteristics. Note 1-3: Gas characteristics refer to toxic (T), oxidized (O), flammable (F), corrosive (C). 1.14 Gas cylinder’s mark The gas cylinder’s mark includes a manufacturing mark and a periodic inspection mark. Manufacturing marks usually have a manufacturing stencils mark (including the mark on the nameplate), a label mark (applied on the cylinder or under a transparent protective layer), a printed mark (printed on the cylinder), a gas cylinder’s color mark; etc. The periodic inspection marks generally include inspection stencils marks, label marks, inspection mark rings, inspection color codes. On the gas cylinder which is used to supply fuel to taxi, it shall have a permanent taxi identification mark (Note 1-4). Note 1-4: For cylinders used for supplying fuel to taxi, the cylinder’s manufacturing organization, installation organization or periodic inspection agency shall, after confirming the purpose of gas cylinder, make a permanent mark of “TAXI” which is representative of Taxi at the prominent position of the gas cylinder’s mark (steel gas cylinders use stencils; wrapped gas cylinders use resin-covered labels). 1.14.1 Gas cylinder’s manufacturing mark 1.14.1.1 Stencils marks, label marks or printed marks of gas cylinders The manufacturing mark of the gas cylinder is the basis for identifying the gas cylinder. The arrangement and content of the marking shall comply with the provisions of Appendix B of this Regulation and corresponding standards. Among them, the manufacturing organization’s code (such as letters, patterns, etc.) shall be reported to the China Gas Cylinder Standardization Organization for future reference. The manufacturing organization shall, in accordance with the provisions of the corresponding standards, make a permanent manufacturing mark on each gas cylinder. Steel gas cylinders or aluminum alloy gas cylinders use stencils. Wrapped gas cylinders use plastic-sealed gas cylinders. Non-refillable gas cylinders are printed on cylinders. Welded insulated gas cylinders (including automotive welded insulated cylinders) and liquefied petroleum gas cylinders are identified by the embossed letter or welding-sealed nameplate. Other products that cannot be marked by the previous method shall use the marking method which complies with the corresponding standards for gas cylinder products. The manufacturing organization shall consider the placement requirements of the information label (bar code, QR code, RF label, etc.) of gas cylinder at the time of design. It is encouraged for the cylinder manufacturing organization or the filling organization to implement the life cycle safety management of the gas cylinders by means of information. 1.14.1.2 Color marks, typeface, color rings on the outer surface of gas cylinder The color mark, typeface, color ring on the outer surface of the gas cylinder shall comply with the provisions of GB 7144 “Colored cylinder mark for gases”. Where there are special requirements for color mark, typeface, color ring, it shall comply with the requirements of the corresponding standards on gas cylinder product. The color, typeface, color ring of gas cylinders which contain gas and mixed gas that are not included in the national standard shall be clearly defined by the national gas cylinder standardization technical organization. Meanwhile it shall be implemented in accordance with the provisions of clause 1.5 of this Regulation. When the liquefied petroleum gas filling organization uses the information label to make management and has more than 300000 liquefied petroleum gas cylinders of self-owned property rights, it shall emboss an obviously raised property right marks on the upper head of the dedicated gas cylinders. The organizations with property rights shall formulate enterprise standards such as the special gas cylinder color marks or the valves and threads of special structural forms. Such standards shall be reviewed by the national gas cylinder standardization technical organization. 1.14.1.3 Marking of welded insulated gas cylinders (including automotive welded insulated gas cylinders) (1) For the gas cylinders which are filled with liquid oxygen (O2), nitrous oxide (N2O), liquefied natural gas (LNG), on an eye-catching position at the head of the outer package, it shall emboss the raised medium symbols such as “O2” and “N2O” or “LNG”; (2) The product nameplate shall be firmly welded to the non-removable accessories; (3) On the cylinder, it shall attach a product label which is consistent with the medium as marked on the nameplate. The background color and text color of the label shall be consistent with the cylinder’s color and text color of the corresponding medium in GB 7144. 1.14.2 Periodic inspection mark of gas cylinder The periodic inspection stencils mark, label mark, inspection mark ring, inspection color code of the gas cylinder shall comply with the provisions of Appendix B of this Regulation. The gas cylinder’s periodic inspection agency shall stamp the inspection qualification stencils on the qualified gas cylinder or make a permanent inspection qualification mark on the gas cylinder one by one. 1.15 Supervisory management (1) The General Administration of Quality Supervision, Inspection and Quarantine and the quality supervision departments at all levels are responsible for the safety supervision of gas cylinders and supervise the implementation of this Regulation; (2) The design, manufacture, filling, inspection, use, etc. of gas cylinders (including gas cylinder’s accessories) shall strictly implement the provisions of this Regulation; (3) The manufacturing, filling, inspection agencies of gas cylinders shall, in accordance with the safety technical specifications and corresponding standards, promptly input relevant data on manufacturing, use registration, filling, inspection into the relevant special equipment information management system. 2 Materials 2.1 Basic requirements (1) The selection of gas cylinder’s materials shall consider the mechanical properties, chemical properties, process properties, compatibility with the medium; (2) The selection of gas cylinder’s materials shall meet the restrictive requirements of the corresponding gas cylinder product standards for materials. The gas cylinder’s materials shall also meet the requirements of the corresponding material standards (Note 2-1); (3) When selecting the metal materials which are not listed in the national standard to manufacture the main part of the gas cylinder, it shall be subject to technical review in accordance with the provisions of 1.6 of this Regulation. The review shall focus on the relevant testing of materials, the test data, the technical documents on trial production of materials (including the technical conditions on product supply), etc.; (4) The material’s manufacturing organization shall make a clear and firm stencil mark on the obvious part of the material or use other methods of marking; (5) The material’s manufacturing organization shall provide the material quality certificate to the material user. The content of the material’s quality certificate shall be complete and clear; and shall have the quality inspection seal of the material manufacturing organization; (6) When the gas cylinder’s manufacturing organization obtains the materials for gas cylinders from the non-material manufacturing organization, it shall obtain the original copy of the quality certificate as provided by the material manufacturer or the duplicated copy of the seal of the material supplier’s official inspection seal and the seal of the responsible person; (7) The cylinder’s manufacturing organization shall be responsible for the authenticity, traceability, consistency of the selected cylinder material and material’s quality certificate. Note 2-1: The corresponding standards as mentioned i...... ......

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