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GB/T 11064.1-2013 (GBT11064.1-2013)

GB/T 11064.1-2013_English: PDF (GBT 11064.1-2013, GBT11064.1-2013)
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GB/T 11064.1-2013English90 Add to Cart 0--9 seconds. Auto-delivery Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride -- Part 1: Determination of lithium carbonate content -- Acid-alkali titrimetric method Valid GB/T 11064.1-2013

BASIC DATA
Standard ID GB/T 11064.1-2013 (GB/T11064.1-2013)
Description (Translated English) Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride - Part 1: Determination of lithium carbonate content - Acid-alkali titrimetric method
Sector / Industry National Standard (Recommended)
Classification of Chinese Standard H64
Classification of International Standard 77.120.99
Word Count Estimation 6,632
Older Standard (superseded by this standard) GB/T 11064.1-1989
Drafting Organization Xinjiang Hao Xin Development Co., lithium salt
Administrative Organization National Nonferrous Metals Standardization Technical Committee
Regulation (derived from) National Standards Bulletin 2013 No. 17
Issuing agency(ies) General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China
Summary This standard specifies: Lithium Carbonate Lithium Carbonate amount determination. This standard applies to: the amount of lithium in the lithium carbonate Determination. Measuring range

Standards related to: GB/T 11064.1-2013

GB/T 11064.1-2003
GB
ICS 77.120.99
H 64
Replacing GB/T 11064.1-1989
Methods for chemical analysis of lithium carbonate,
lithium hydroxide monohydrate and lithium chloride -
Part 1. Determination of lithium carbonate content -
Acid-alkali titrimetric method
ISSUED ON. SEPTEMBER 05, 2013
IMPLEMENTED ON. MAY 01, 2014
Issued by.
General Administration of Quality Supervision, Inspection
and Quarantine of the People’s Republic of China;
Standardization Administration of the People’s Republic of
China.
Table of Contents
Foreword ... 3 
1 Scope ... 5 
2 Method summary ... 5 
3 Reagents ... 5 
4 Samples ... 6 
5 Analysis steps... 6 
6 Calculation of analysis results ... 7 
7 Precision ... 8 
8 Test report ... 8 
Foreword
GB/T 11064 "Methods for chemical analysis of lithium carbonate, lithium hydroxide
monohydrate and lithium chloride" is divided into 16 parts.
- Part 1. Determination of lithium carbonate content - Acid-alkali titrimetric method;
- Part 2. Determination of lithium hydroxide content - Acid-alkali titrimetric method;
- Part 3. Determination of lithium chloride content - Potentiometric method;
- Part 4. Determination of potassium and sodium content - Flame atomic
absorption spectrometric method;
- Part 5. Determination of calcium content - Flame atomic absorption spectrometric
method;
- Part 6. Determination of magnesium content - Flame atomic absorption
spectrometric method;
- Part 7. Determination of iron content - 1,10-phenanthroline spectrophotometric
method;
- Part 8. Determination of silicon content - Molybdenum blue spectrophotometric
method;
- Part 9. Determination of sulfate content - Barium sulfate nephelometry method;
- Part 10. Determination of chloride content - Silver chloride nephelometry method;
- Part 11. Determination of Acid-insolubles Content - Gravimetric method;
- Part 12. Determination of carbonate content - Determination of lithium chloride
content - Potentiometric method;
- Part 13. Determination of aluminum content - Chromazurol S-cetylpyridine
bromide spectrophotometric method;
- Part 14. Determination of arsenic content - Molybdenum blue spectrophotometric
method;
- Part 15. Determination of fluoride content - Ion selective method;
- Part 16. Determination of calcium, magnesium, copper, lead, zinc, nickel,
manganese, cadmium and aluminum content - Inductively coupled plasma
atomic emission spectrometry.
This Part is part 1 of GB/T 11064.
This Part is drafted in accordance with the rules given in GB/T 1.1-2009.
The Part replaces GB/T 11064.1-1989 “Methods for chemical analysis of lithium
carbonate, lithium hydroxide monohydrate and lithium chloride - Part 1. Determination
of lithium carbonate content - Acid-alkali titrimetric method”.
Compared with GB/T 11064.1-1989, the main changes of this Part are following.
— ADD the repeatability terms;
— RE-EDIT the text format; ADD the test report.
This Part shall be under the jurisdiction of National Standardization Technical
Committee of Nonferrous Metals (SAC/TC 243).
Drafting organizations of this Part. Xinjiang Wuxin Lithium Salt Development Co., Ltd.,
Sichuan Tianqi Lithium Co., Ltd., Jiangxi Dongpeng New Materials Co., Ltd., Xinjiang
Institute of Nonferrous Metals, and Beijing General Research Institute of Mining and
Metallurgy.
Main drafters of this Part. Zeng Xianqin, Xia Shufen, Gou Haixia, Luo Yuping, Zhong
Haihua, Guan Yuzhen, and Feng Xianjin.
The historical version replaced by this Part is as follows.
— GB/T 11064.1-1989.
Methods for chemical analysis of lithium carbonate, lithium
hydroxide monohydrate and lithium chloride - Part 1.
Determination of lithium carbonate content –
Acid-alkali titrimetric method
1 Scope
This Part of GB/T 11064 specifies the determination method for lithium carbonate
content in lithium carbonate.
This Part applies to the determination of lithium carbonate content in lithium carbonate.
The determination range. more than 95.00%.
2 Method summary
The sample is dissolved in a certain amount of hydrochloric acid standard titration
solution; use methyl red - bromocresol green as the indicator; use hydrochloric acid
standard titration solution to titrate the total alkalinity of the test solution; use the
consumed amount of hydrochloric acid standard titration solution to calculate the
content of lithium carbonate. Calcium content in test sample shall be converted to
lithium carbonate content, then subtracted from the calculation result.
3 Reagents
Unless otherwise indicated, all reagents used in this Part are analytical reagent, the
water used is deionized water.
3.1 Methyl red - bromocresol green indicator. Pipette 30mL of bromocresol green
solution (3.1.1) and 10mL of methyl red solution (3.1.2); mix well.
3.1.1 Bromocresol green solution. Weigh 0.1g of bromocresol green; dissolve it in
100mL of ethanol (95%) solution.
3.1.2 Methyl red solution. Weigh 0.2g of methyl red; dissolve it in 100mL of ethanol
(95%) solution.
3.2 Hydrochloric acid standard titration solution [c(HCI) = 0.30mol/L].
7 Precision
7.1 Repeatability
For the two independent test results obtained under repeatability conditions, within the
average-value range as given below, the absolute difference of these two test results
does not exceed the repeatability limit (r), and the situation exceeding repeatability
limit (r) is not more than 5%. Repeatability limit (r), according to Table 1, adopts linear
interpolation to obtain.
Table 1
wLi2CO3/% 95.60 97.46 99.40
r/% 0.15 0.15 0.16
7.2 Allowable difference
The difference of analysis results among laboratories shall not be more than the
allowable difference in Table 2.
Table 2
Mass fraction of lithium carbonate/% Allowable difference/%
>95.00 0.30
8 Test report
The test report shall contain the following content.
— Sample;
— The number of this Part national standard;
— Analysis result and its expression;
— Difference with the basic analysis step;
— Anomalies observed in the determination;
— Determination date.
...