HJ 2515-2012 PDF English
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Technical requirement for environmental labeling products - Ship anti-fouling paints
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HJ 2515-2012: PDF in English HJ 2515-2012
HJ
ENVIRONMENTAL PROTECTION STANDARD
OF THE PEOPLE’S REPUBLIC OF CHINA
Technical requirement for environmental
labeling products - Ship anti-fouling paints
ISSUED ON: JULY 3, 2012
IMPLEMENTED ON: OCTOBER 1, 2012
Issued by: Ministry of Environmental Protection
Table of Contents
Foreword ... 3
1 Scope ... 4
2 Normative references ... 4
3 Terms and definitions ... 5
4 Basic requirements ... 5
5 Technical contents ... 5
6 Test methods ... 7
Annex A (informative) List of low-risk active substances in ship anti-fouling
paints ... 8
Annex B (informative) Marine environmental risk assessment method for active
substances in ship anti-fouling paints ... 9
Foreword
This Standard is formulated for the purpose of implementing the Environmental
Protection Law of the People's Republic of China, reducing the effects of ship
anti-fouling paints on the environment and human health during production and
use, and protecting the environment.
This Standard puts forward requirements for the prohibited substances, limits
of hazardous substances in ship anti-fouling paints, and the use instructions.
This is the first release of this Standard.
This Standard applies to China Environmental Labeling Product Certification.
This Standard was formulated by Department of Science and Technology
Standards of the Ministry of Environmental Protection.
Mainly drafting organization of this Standard: China-Japan Friendship
Environmental Protection Center, Environmental Protection Cooperation
Center of the Ministry of Environmental Protection.
This Standard was approved by Ministry of Environmental Protection on July 3,
2012.
This Standard has been implemented since October 1, 2012.
This Standard is explained by Ministry of Environmental Protection.
Technical requirement for environmental
labeling products - Ship anti-fouling paints
1 Scope
This Standard specifies the terms and definitions, basic requirements, technical
contents and inspection methods of environmental labeling products of ship
anti-fouling paints.
This Standard applies to all types of ship anti-fouling paints.
2 Normative references
The following documents contain the provisions which, through reference in this
Standard, become the provisions of this Standard. For undated references, the
valid versions apply to this Standard.
GB 16483 Safety data sheet for chemical products content and order of
sections
GB 17378.5-2007 The specification for marine monitoring - Part 5: Sediment
analysis
GB 18581-2009 Indoor decorating and refurbishing materials - Limit of
harmful substances of solvent based coatings for woodenware
GB 18582-2008 Indoor decorating and refurbishing materials - Limit of
harmful substances of interior architectural coatings
GB 24613-2009 Limit of harmful substances of coatings for toys
GB/T 6824-2008 Determination for release rate of cupper-ion for antifouling
paint on ship bottom
GB/T 21815.1-2008 Testing of chemicals - Biodegradability in seawater -
Shake flask method
GB/T 25011-2010 Test method and determination for DDT content of marine
antifouling paints
GB/T 26085-2010 Test method and determination of total tin in antifouling
paints for ship
HJ/T 153-2004 The guidelines for the testing of chemicals
3 Terms and definitions
For the purpose of this Standard, the following terms and definitions apply.
3.1 ship anti-fouling paints
It refers to coatings used for ship to control or prevent the attachment of
unfavorable organisms.
3.2 active substances
It refers to compounds that have a general or specific effect on fouling
organisms in anti-fouling paints.
3.3 environmental risk assessment
Quantitatively or qualitatively put forward the potential environmental impact of
the substance by examining exposure due to chemical emissions or releases
and the effects of such exposure on ecosystem structure and action.
4 Basic requirements
4.1 The product quality shall meet the requirements of the corresponding
product quality standards.
4.2 Pollutant emissions from product manufacturing enterprises shall comply
with national or local standards for pollutant emissions.
4.3 Product manufacturing enterprises shall strengthen clean production in the
production process.
5 Technical contents
5.1 General requirements for products
5.1.1 The substances listed in Table 1 shall not be artificially added.
following:
(1) The implemented quality standard(s).
(2) The active substance(s) used.
(3) The manufacturing enterprise shall provide a Material Safety Data Sheet
(MSDS) that meets the requirements of GB 16483.
6 Test methods
6.1 The determination of volatile organic compounds, toluene + xylene +
ethylbenzene and benzene in the technical content 5.1.2 is carried out
according to the method specified in GB 18581-2009.
6.2 The determination of lead (Pb), cadmium (Cd), chromium (Cr) in the
technical content 5.1.2 is carried out according to the method specified in GB
18582-2008; the determination of arsenic (As) is carried out according to the
method specified in GB 24613-2009.
6.3 The determination of DDT in the technical content 5.2.1 is carried out
according to the method specified in GB/T 25011-2010.
6.4 The determination of mercury (Hg) in the technical content 5.2.1 is carried
out according to the method specified in GB 18582-2008.
6.5 The determination of total tin content in the technical content 5.2.2 is carried
out according to the method specified in GB/T 26085-2010.
6.6 The determination of copper ion bleed rate in the technical content 5.2.3 is
carried out according to the method specified in GB/T 6824-2008.
6.7 Other indicators in the technical content are verified by means of document
review combined with on-site inspection.
Annex B
(informative)
Marine environmental risk assessment method
for active substances in ship anti-fouling paints
B.1 Method principle
The marine environmental risk assessment of active substances in anti-fouling
paints shall be carried out in terms of persistence, bioaccumulation and toxicity.
When the active substance meets the persistence, bioaccumulation and toxicity
assessment criteria mentioned below, it is relatively low risk in the marine
environment.
(1) Persistence assessment criteria: ① the active substance has “rapid
biodegradability”; or ② the mineralization half-life of the active
substance is less than 60 days; or ③ the degradation half-life of the
active substance is less than 60 days and the bactericidal activity of the
active substance is gradually reduced during the degradation process;
(2) Bioaccumulation assessment criteria: 1g(Kow) < 4 or the highest BCF <
500;
(3) Toxicity assessment criteria: when Koc < 1000 L/kg, PEC/PNEC < 1 in
seawater medium; when Koc ≥ 1000 L/kg, PEC/PNEC < 1 in seawater
and sediment media.
B.2 Assessment indicators
B.2.1 Persistence assessment criteria
B.2.1.1 Rapid biodegradability
Carry out the test according to “301: Rapid biodegradability” in HJ/T 153-2004.
If the test result is positive, then the active substance has rapid biodegradability.
B.2.1.2 Mineralization half-life and degradation half-life of the active
substance
Carry out the test according to GB/T 21815.1-2008 to determine the
mineralization half-life and degradation half-life of the active substance.
B.2.1.3 The bactericidal activity of the active substance is gradually
reduced during the degradation process
......
Source: Above contents are excerpted from the PDF -- translated/reviewed by: www.chinesestandard.net / Wayne Zheng et al.
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